База данных: Статьи
Страница 3, Результатов: 29
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21.
Подробнее
35
D99
Dzhumadullaeva, S. A.
The kinetics of selective hydrazinolysis of maleic acid on the acid catalyst. [Текст] / S. A. Dzhumadullaeva, A. B. Bayeshov, A. V. Kolesnikov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 53-57
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
maleic acid -- hydrazinolysis -- hydrazide -- catalyst
Аннотация: For the first time, kinetics and the mechanism of the reaction of hydrazinolysis of maleic acid in the presence of cation exchanger resin KU-2-8 in H-form have been studied. The experiments were carried out in a static system in a thermostat glass reactor. It was found that cation exchanger shows high catalytic activity in the studied process - maleic acid conversion was 93%, and maleic hydrazide yield was 90%. The conversion selectivity of maleic acid to maleic hydrazide was 97,8%. The reaction rate was determined from the accumulation of maleic hydrazide. The apparent reaction rate constant (k) was calculated from the second-order reaction rate equation. The effect of initial concentrations of maleic acid and hydrazine hydrate, the temperature on the reaction rate was studied. The first order of maleic acid and hydrazine hydrate is determined. Activation energy of the process found from the Arrhenius dependence is 32,1 kJ/mol. On the basis of kinetic and IR spectroscopic methods, a probable reaction mechanism involving polymer-bound hydrogen ions is proposed.
Держатели документа:
WKU
Доп.точки доступа:
Bayeshov, A.B.
Kolesnikov, A.V.
D99
Dzhumadullaeva, S. A.
The kinetics of selective hydrazinolysis of maleic acid on the acid catalyst. [Текст] / S. A. Dzhumadullaeva, A. B. Bayeshov, A. V. Kolesnikov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 53-57
Рубрики: chemical Technology
Кл.слова (ненормированные):
maleic acid -- hydrazinolysis -- hydrazide -- catalyst
Аннотация: For the first time, kinetics and the mechanism of the reaction of hydrazinolysis of maleic acid in the presence of cation exchanger resin KU-2-8 in H-form have been studied. The experiments were carried out in a static system in a thermostat glass reactor. It was found that cation exchanger shows high catalytic activity in the studied process - maleic acid conversion was 93%, and maleic hydrazide yield was 90%. The conversion selectivity of maleic acid to maleic hydrazide was 97,8%. The reaction rate was determined from the accumulation of maleic hydrazide. The apparent reaction rate constant (k) was calculated from the second-order reaction rate equation. The effect of initial concentrations of maleic acid and hydrazine hydrate, the temperature on the reaction rate was studied. The first order of maleic acid and hydrazine hydrate is determined. Activation energy of the process found from the Arrhenius dependence is 32,1 kJ/mol. On the basis of kinetic and IR spectroscopic methods, a probable reaction mechanism involving polymer-bound hydrogen ions is proposed.
Держатели документа:
WKU
Доп.точки доступа:
Bayeshov, A.B.
Kolesnikov, A.V.
22.
Подробнее
35
K17
Kairbekov, Zh. K.
Investigation of the catalytic and isomerization activity of multi-component skeletal nickel catalysts in the hydrogenation of hexene -1. [Текст] / Zh. K. Kairbekov, S. M. Suimbayeva, I. M. Jeldybayeva, E. T. Yermoldina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - p. 58-64
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
catalyst -- hydrogenation -- hexеne-1 -- skeletal nickel -- activity -- selectivity -- migration -- alloy
Аннотация: In this work, the effect of the amount of catalyst, modifying additives, and the phase composition of the alloys on the catalytic and isomerizing activity of skeletal in the hydrogenation reaction of hexane-1 is investigated.
Держатели документа:
WKU
Доп.точки доступа:
Suimbayeva, S. M.
Jeldybayeva, I. M.
Yermoldina, E. T.
K17
Kairbekov, Zh. K.
Investigation of the catalytic and isomerization activity of multi-component skeletal nickel catalysts in the hydrogenation of hexene -1. [Текст] / Zh. K. Kairbekov, S. M. Suimbayeva, I. M. Jeldybayeva, E. T. Yermoldina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - p. 58-64
Рубрики: chemical Technology
Кл.слова (ненормированные):
catalyst -- hydrogenation -- hexеne-1 -- skeletal nickel -- activity -- selectivity -- migration -- alloy
Аннотация: In this work, the effect of the amount of catalyst, modifying additives, and the phase composition of the alloys on the catalytic and isomerizing activity of skeletal in the hydrogenation reaction of hexane-1 is investigated.
Держатели документа:
WKU
Доп.точки доступа:
Suimbayeva, S. M.
Jeldybayeva, I. M.
Yermoldina, E. T.
23.
Подробнее
35
A92
Augaliev, D. B.
Oxidative dimerization of methane to C2 hydrocarbons. [Текст] / D. B. Augaliev, M. K. Erkibaeva, A. O. Aidarova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 18-24
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
ODM reaction -- C2 hydrocarbons -- SHS method -- temperature of reaction
Аннотация: The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce-20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction.
Держатели документа:
WKU
Доп.точки доступа:
Erkibaeva, M.K.
Aidarova, A.O.
Tungatarova, S.А.
Baizhumanova, T.S.
A92
Augaliev, D. B.
Oxidative dimerization of methane to C2 hydrocarbons. [Текст] / D. B. Augaliev, M. K. Erkibaeva, A. O. Aidarova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 18-24
Рубрики: chemical Technology
Кл.слова (ненормированные):
ODM reaction -- C2 hydrocarbons -- SHS method -- temperature of reaction
Аннотация: The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce-20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction.
Держатели документа:
WKU
Доп.точки доступа:
Erkibaeva, M.K.
Aidarova, A.O.
Tungatarova, S.А.
Baizhumanova, T.S.
24.
Подробнее
24
M97
Mussina, А. S.
Development of the conditions for strong thallium amalgam. [Текст] / А. S. Mussina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 65-70
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
thallium amalgam -- chemical preparation -- storage -- decomposition -- sulfuric acid -- water -- wash liquid
Аннотация: It has been established that lNH2SO4 solution and distilled water can be used as a protective medium for a long-term storage (30-40 days) of thallium amalgam of eutectic composition (8.6 mas.%), without sliming of its surface and an insignificant change of its concentration. An inverse dependence between the decomposition reaction rate and the ratio of the solution volume per unit of the contact surface (V:S), which corresponds to the height of the liquid layer (h) above the amalgam, is observed. At h ~ 2.5 cm and higher, the reaction rate becomes stabilized. The value of metal loss during its storage for 10-15 days does not exceed 0.5-1.0 mas.% of the initial thallium content in the amalgam. It has been shown that the rate of dissolution of thallium from amalgam is rather low, and in sulfuric acid solution it is only slightly higher than that in water with all S:V ratios. A similar picture is observed upon thallium amalgam decomposition in the same media in an open vessel; the difference consists only in a higher K value (Table 4). Thus, with S:V = 1:2.5, in an open vessel K in lNH2SO4 makes up 10,5.1011 mol/cm2.sec, and in H2O – 7.3.1011 mol/cm2.sec, whereas in a closed vessel K in lNH2SO4 makes up 1,9.1011 mol/cm2.sec, and in H2O – 1.5.1011 mol/cm2.sec. For 40 days of thallium amalgam (8.54 mas.%) storage in 1NH2SO4 the loss of thallium has been 1.3 mas.%, and in the distilled water - 1 mas.%. The quantity of the dissolved metal increases in proportion to the experiment duration, which is characteristic for a zero-order reaction, and this dependence is observed for all S:V ratios from 1:1 to 1:7. Besides, a possibility to use some saturated hydrocarbons, wherein no sliming of thallium amalgam occurs, as a protective wash liquid has been shown.
Держатели документа:
WKU
Доп.точки доступа:
Baitasheva, G.U.
Myrzakhmetova, N.О.
Tagabergenova, Zh.A.
Gorbulicheva , E.P.
M97
Mussina, А. S.
Development of the conditions for strong thallium amalgam. [Текст] / А. S. Mussina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 65-70
Рубрики: chemistry
Кл.слова (ненормированные):
thallium amalgam -- chemical preparation -- storage -- decomposition -- sulfuric acid -- water -- wash liquid
Аннотация: It has been established that lNH2SO4 solution and distilled water can be used as a protective medium for a long-term storage (30-40 days) of thallium amalgam of eutectic composition (8.6 mas.%), without sliming of its surface and an insignificant change of its concentration. An inverse dependence between the decomposition reaction rate and the ratio of the solution volume per unit of the contact surface (V:S), which corresponds to the height of the liquid layer (h) above the amalgam, is observed. At h ~ 2.5 cm and higher, the reaction rate becomes stabilized. The value of metal loss during its storage for 10-15 days does not exceed 0.5-1.0 mas.% of the initial thallium content in the amalgam. It has been shown that the rate of dissolution of thallium from amalgam is rather low, and in sulfuric acid solution it is only slightly higher than that in water with all S:V ratios. A similar picture is observed upon thallium amalgam decomposition in the same media in an open vessel; the difference consists only in a higher K value (Table 4). Thus, with S:V = 1:2.5, in an open vessel K in lNH2SO4 makes up 10,5.1011 mol/cm2.sec, and in H2O – 7.3.1011 mol/cm2.sec, whereas in a closed vessel K in lNH2SO4 makes up 1,9.1011 mol/cm2.sec, and in H2O – 1.5.1011 mol/cm2.sec. For 40 days of thallium amalgam (8.54 mas.%) storage in 1NH2SO4 the loss of thallium has been 1.3 mas.%, and in the distilled water - 1 mas.%. The quantity of the dissolved metal increases in proportion to the experiment duration, which is characteristic for a zero-order reaction, and this dependence is observed for all S:V ratios from 1:1 to 1:7. Besides, a possibility to use some saturated hydrocarbons, wherein no sliming of thallium amalgam occurs, as a protective wash liquid has been shown.
Держатели документа:
WKU
Доп.точки доступа:
Baitasheva, G.U.
Myrzakhmetova, N.О.
Tagabergenova, Zh.A.
Gorbulicheva , E.P.
25.
Подробнее
24
N94
Nurdillayeva, R. N.
Dissolution of stanless steel in sodium chloride solution at polarization by non-stationary current. [Текст] / R. N. Nurdillayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 75-81
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
stainless steel -- titanium electrode -- alternating current -- iron (II) ions -- chromium (III)ions -- current density -- and current efficiency
Аннотация: Stainless steel is in great demand due to its mechanical strength, heat resistance, and resistance to corrosive environments. This article presents the result of a study of the electrochemical dissolution behavior of a stainless steel electrode (12X18H10T) at polarization by 50 Hz alternating current in a neutral medium (NaCl). Preliminary experiments have shown that the main processes do not take place when two stainless steel electrodes are polarized with an alternating current. It was observed that by the polarization of the “stainless steel – titanium” pair electrodes with alternating current, the alloy is intensively dissolved with the formation of iron (II) and chromium (III) ions. This is due to the "valve" properties of the oxide layer formed on the surface of the titanium electrode. A change in the value of the current density of the titanium and steel electrodes significantly affects the process of electrochemical dissolution of the alloy. At high current densities, the dissolution rate of the alloy decreases due to the deterioration of the current correcting properties of titanium. With an increase in the electrolyte concentration, the current efficiency is reduced as salt passivation occurs. A maximum value of the current efficiency of dissolution of stainless steel was observed at a current frequency of 50 Hz. High frequencies of the alternating current do not provide an adjustable duration of the anodic half-cycle for the oxidation reaction due to the frequent change of half-cycles of the alternating current. It was observed that increasing the temperature of the electrolyte reduces the current efficiency of the electrochemical dissolution of stainless steel electrodes. The effects of main electrochemical parameters on the electrolysis process have been investigated, and the optimal conditions of the alloy dissolution were established (іТі = 60 kA/m2, іSS = 800 A/m2, [NaCl] = 2.0 M, t = 30, ν = 50 Hz.).
Держатели документа:
WKU
Доп.точки доступа:
Sauirbay, Zh.G.
Bayeshov, A.B.
N94
Nurdillayeva, R. N.
Dissolution of stanless steel in sodium chloride solution at polarization by non-stationary current. [Текст] / R. N. Nurdillayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 75-81
Рубрики: chemistry
Кл.слова (ненормированные):
stainless steel -- titanium electrode -- alternating current -- iron (II) ions -- chromium (III)ions -- current density -- and current efficiency
Аннотация: Stainless steel is in great demand due to its mechanical strength, heat resistance, and resistance to corrosive environments. This article presents the result of a study of the electrochemical dissolution behavior of a stainless steel electrode (12X18H10T) at polarization by 50 Hz alternating current in a neutral medium (NaCl). Preliminary experiments have shown that the main processes do not take place when two stainless steel electrodes are polarized with an alternating current. It was observed that by the polarization of the “stainless steel – titanium” pair electrodes with alternating current, the alloy is intensively dissolved with the formation of iron (II) and chromium (III) ions. This is due to the "valve" properties of the oxide layer formed on the surface of the titanium electrode. A change in the value of the current density of the titanium and steel electrodes significantly affects the process of electrochemical dissolution of the alloy. At high current densities, the dissolution rate of the alloy decreases due to the deterioration of the current correcting properties of titanium. With an increase in the electrolyte concentration, the current efficiency is reduced as salt passivation occurs. A maximum value of the current efficiency of dissolution of stainless steel was observed at a current frequency of 50 Hz. High frequencies of the alternating current do not provide an adjustable duration of the anodic half-cycle for the oxidation reaction due to the frequent change of half-cycles of the alternating current. It was observed that increasing the temperature of the electrolyte reduces the current efficiency of the electrochemical dissolution of stainless steel electrodes. The effects of main electrochemical parameters on the electrolysis process have been investigated, and the optimal conditions of the alloy dissolution were established (іТі = 60 kA/m2, іSS = 800 A/m2, [NaCl] = 2.0 M, t = 30, ν = 50 Hz.).
Держатели документа:
WKU
Доп.точки доступа:
Sauirbay, Zh.G.
Bayeshov, A.B.
26.
Подробнее
35
R24
Rasulov, S. R.
Development of effective catalysts for processing C3-C4 Hydrocarbons. [Текст] / S. R. Rasulov, G. R. Mustafayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 87-93
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
refinery gases -- 3-C4 hydrocarbons -- zeolite-containing catalyst -- modifiers -- reaction-regeneration cycles.
Аннотация: The aim of the article is to study the effect of preparation and activation methods of a modified zeolite-containing catalyst on the activity and stability of catalytic properties displayed by it during the conversion of C3-C4 hydrocarbons. During the experiment, the industrial cracking catalyst OMNIKAT, which is a zeolite in the sodium form, was used as the initial one. Zinc, gallium, and REE (rare earth elements) were sequentially applied to decationized samples of this catalyst by ion exchange, impregnation, and dry mechanical mixing, and the effect of these methods on the catalytic properties of the zeolite-containing catalyst was observed. As a result of a comparative analysis of the regularities of aromatization of C3-C4hydrocarbons, it was found that the mechanical mixing method is the most preferable, since it provides the best process performance.
Держатели документа:
WKU
Доп.точки доступа:
Mustafayeva, G.R.
R24
Rasulov, S. R.
Development of effective catalysts for processing C3-C4 Hydrocarbons. [Текст] / S. R. Rasulov, G. R. Mustafayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 87-93
Рубрики: chemical Technology
Кл.слова (ненормированные):
refinery gases -- 3-C4 hydrocarbons -- zeolite-containing catalyst -- modifiers -- reaction-regeneration cycles.
Аннотация: The aim of the article is to study the effect of preparation and activation methods of a modified zeolite-containing catalyst on the activity and stability of catalytic properties displayed by it during the conversion of C3-C4 hydrocarbons. During the experiment, the industrial cracking catalyst OMNIKAT, which is a zeolite in the sodium form, was used as the initial one. Zinc, gallium, and REE (rare earth elements) were sequentially applied to decationized samples of this catalyst by ion exchange, impregnation, and dry mechanical mixing, and the effect of these methods on the catalytic properties of the zeolite-containing catalyst was observed. As a result of a comparative analysis of the regularities of aromatization of C3-C4hydrocarbons, it was found that the mechanical mixing method is the most preferable, since it provides the best process performance.
Держатели документа:
WKU
Доп.точки доступа:
Mustafayeva, G.R.
27.
Подробнее
31.46
C16
Calculation and design of an industrial reactor for pyrroles synthesis [Текст] / U. Shokirov, S. Turabdjanov, H. Kadirov [и др.] // Известия Национальной Академии наук Республики Казахстан. - 2021. - №1. - Р. 157-163
ББК 31.46
Рубрики: Ядерные реакторы. Реакторостроение
Кл.слова (ненормированные):
пиррол -- ацетилен -- аммиак -- амины -- катализатор -- дегидратация -- гетероциклизация
Аннотация: Производство синтеза пирролов на основе ацетилена, аммиака и аминов в присутствии полифункциональных катализаторов может быть организовано только тогда, когда для его получения разработана рациональная промышленная технология, позволяющая достаточно дешево из доступного сырья получать этот продукт в необходимом количестве и требуемого качества. В статье рассматриваются вопросы, связанные с разработкой нового реактора, обладающего высокой производительностью и экономической эффективностью. Были также изучены процессы, протекающие в реакторе. Исследованы фазовые характеристики в ответ на изменение скорости конверсии ацетилена в зависимости от высоты слоя катализатора. В результате достигается высокая производительность производства ацетилена с цинк-хромалюминиевым катализатором в интервале температур 340-440 ° с на 92% при высоте слоя 1200 мм от верхней точки реактора. На основе баланса масс, а также результатов эксперимента предложен реактор для промышленного синтеза пирролов
Держатели документа:
ЗКУ
Доп.точки доступа:
Shokirov, U.
Turabdjanov, S.
Kadirov, H.
Badriddinova, F.
Kedelbaev, B.
C16
Calculation and design of an industrial reactor for pyrroles synthesis [Текст] / U. Shokirov, S. Turabdjanov, H. Kadirov [и др.] // Известия Национальной Академии наук Республики Казахстан. - 2021. - №1. - Р. 157-163
Рубрики: Ядерные реакторы. Реакторостроение
Кл.слова (ненормированные):
пиррол -- ацетилен -- аммиак -- амины -- катализатор -- дегидратация -- гетероциклизация
Аннотация: Производство синтеза пирролов на основе ацетилена, аммиака и аминов в присутствии полифункциональных катализаторов может быть организовано только тогда, когда для его получения разработана рациональная промышленная технология, позволяющая достаточно дешево из доступного сырья получать этот продукт в необходимом количестве и требуемого качества. В статье рассматриваются вопросы, связанные с разработкой нового реактора, обладающего высокой производительностью и экономической эффективностью. Были также изучены процессы, протекающие в реакторе. Исследованы фазовые характеристики в ответ на изменение скорости конверсии ацетилена в зависимости от высоты слоя катализатора. В результате достигается высокая производительность производства ацетилена с цинк-хромалюминиевым катализатором в интервале температур 340-440 ° с на 92% при высоте слоя 1200 мм от верхней точки реактора. На основе баланса масс, а также результатов эксперимента предложен реактор для промышленного синтеза пирролов
Держатели документа:
ЗКУ
Доп.точки доступа:
Shokirov, U.
Turabdjanov, S.
Kadirov, H.
Badriddinova, F.
Kedelbaev, B.
28.
Подробнее
22.2
G 42
Gholamreza, R.
Continuum mechanics: applications in bone remodeling and bone resorption models [Текст] / R. // Вестник Национальной инженерной академии Республики Казахстан. - 2021. - №3. - с. 70-78
ББК 22.2
Рубрики: Механика
Кл.слова (ненормированные):
continuum mechanics -- biomechanics -- bone cells -- remodeling -- resosrption -- mixture theories -- chemical reactions
Аннотация: A brief description of continuum mechanics is given, first. Then, a general introduction on biomechanics is presented, along with some salient features of it, which should be kept in mind when one is working in this field. The manuscript will continue with an introduction on bone remodelling process, then some phenomenological models on the bone remodelling, process will be introduced.
Держатели документа:
ЗКУ им М. Утемисова
G 42
Gholamreza, R.
Continuum mechanics: applications in bone remodeling and bone resorption models [Текст] / R. // Вестник Национальной инженерной академии Республики Казахстан. - 2021. - №3. - с. 70-78
Рубрики: Механика
Кл.слова (ненормированные):
continuum mechanics -- biomechanics -- bone cells -- remodeling -- resosrption -- mixture theories -- chemical reactions
Аннотация: A brief description of continuum mechanics is given, first. Then, a general introduction on biomechanics is presented, along with some salient features of it, which should be kept in mind when one is working in this field. The manuscript will continue with an introduction on bone remodelling process, then some phenomenological models on the bone remodelling, process will be introduced.
Держатели документа:
ЗКУ им М. Утемисова
29.
Подробнее
3
К 43
Киргизбаев, С.
Изучение изоморфных фреймворков JAVASCRIPT и одностраничных приложений [Текст] / С. Киргизбаев // Транзитная экономика. - 2023. - №2. - С. 112-120.
ББК 3
Рубрики: Техника.
Кл.слова (ненормированные):
изучение -- одностраничное приложение -- SPA -- веб-сайт -- динамические данные -- фреймворки -- React -- Vue
Аннотация: Конечная цель нашего проекта-создание приложения электронного магазина.
Держатели документа:
ЗКУ
К 43
Киргизбаев, С.
Изучение изоморфных фреймворков JAVASCRIPT и одностраничных приложений [Текст] / С. Киргизбаев // Транзитная экономика. - 2023. - №2. - С. 112-120.
Рубрики: Техника.
Кл.слова (ненормированные):
изучение -- одностраничное приложение -- SPA -- веб-сайт -- динамические данные -- фреймворки -- React -- Vue
Аннотация: Конечная цель нашего проекта-создание приложения электронного магазина.
Держатели документа:
ЗКУ
Страница 3, Результатов: 29