База данных: Статьи
Страница 2, Результатов: 28
Отмеченные записи: 0
11.
Подробнее
24
K70
Koleskin, V. N.
The solving of the problem in the working zone. The numerical calculation of the model of the nizhnekamsk reactor for the styene production (Part -3). [Текст] / V. N. Koleskin // News of the national academy of sciences of the Kazakhstan. . - 2021. - №1. - P. 6-13
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
chemical reactor -- still granular layer -- catalyst -- ergun law -- stream function -- granular layer resistance factor -- Green's function pressure field -- velocity field -- layer resistance
Аннотация: The article deals with a mathematical modeling of an incompressible liquidflow in flat and radial contact units with the still granular layer and a creation on numerical realzation methods for the model.
Держатели документа:
WKU
Доп.точки доступа:
Yunusov, A.A.
Yunusova, A.A.
Shtern, P.G.
Lukyanova, A.V.
Zhmadullayev, D.K.
Ainamkulova, T.S.
Bugibaev, E.T.
K70
Koleskin, V. N.
The solving of the problem in the working zone. The numerical calculation of the model of the nizhnekamsk reactor for the styene production (Part -3). [Текст] / V. N. Koleskin // News of the national academy of sciences of the Kazakhstan. . - 2021. - №1. - P. 6-13
Рубрики: chemistry
Кл.слова (ненормированные):
chemical reactor -- still granular layer -- catalyst -- ergun law -- stream function -- granular layer resistance factor -- Green's function pressure field -- velocity field -- layer resistance
Аннотация: The article deals with a mathematical modeling of an incompressible liquidflow in flat and radial contact units with the still granular layer and a creation on numerical realzation methods for the model.
Держатели документа:
WKU
Доп.точки доступа:
Yunusov, A.A.
Yunusova, A.A.
Shtern, P.G.
Lukyanova, A.V.
Zhmadullayev, D.K.
Ainamkulova, T.S.
Bugibaev, E.T.
12.
Подробнее
24
N94
Nurdillayeva, R. N.
Electrochemical behavior of cupronickel electrode in acidic media. [Текст] / R. N. Nurdillayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 38-46
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
cupronickel -- Cu-Ni alloy -- alternating current -- titanium electrode -- hydrochloric acid -- electrolysis -- current density -- current efficiency
Аннотация: The electrochemical properties of the cupronickel electrode polarized by an alternating current in an aqueous solution of hydrochloric acid were studied for the first time. The electrochemical dissolution of cupronickel was carried out in a polarization mode with a frequency of 50 Hz in pairs with a titanium electrode. The current efficiency of dissolution of Cu-Ni alloys dependence on the current density at the titanium (20-120 kA/m2) and cupronickel (200-1200 A/m2) electrodes, the concentration of a hydrochloric acid solution (0.5-5.0 M), the electrolysis duration (0.5-1.75 h) and the alternating current effect (50-300 Hz) were considered. It was observed that the current efficiency of the alloy dissolution decreases linearly with increasing current density at the cupronickel electrode, while the current density at the titanium electrode passes through a maximum value at 60 kA/m2.
Держатели документа:
WKU
Доп.точки доступа:
Abdilda, N. Sh.
Bayeshov, A.B.
N94
Nurdillayeva, R. N.
Electrochemical behavior of cupronickel electrode in acidic media. [Текст] / R. N. Nurdillayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 38-46
Рубрики: chemistry
Кл.слова (ненормированные):
cupronickel -- Cu-Ni alloy -- alternating current -- titanium electrode -- hydrochloric acid -- electrolysis -- current density -- current efficiency
Аннотация: The electrochemical properties of the cupronickel electrode polarized by an alternating current in an aqueous solution of hydrochloric acid were studied for the first time. The electrochemical dissolution of cupronickel was carried out in a polarization mode with a frequency of 50 Hz in pairs with a titanium electrode. The current efficiency of dissolution of Cu-Ni alloys dependence on the current density at the titanium (20-120 kA/m2) and cupronickel (200-1200 A/m2) electrodes, the concentration of a hydrochloric acid solution (0.5-5.0 M), the electrolysis duration (0.5-1.75 h) and the alternating current effect (50-300 Hz) were considered. It was observed that the current efficiency of the alloy dissolution decreases linearly with increasing current density at the cupronickel electrode, while the current density at the titanium electrode passes through a maximum value at 60 kA/m2.
Держатели документа:
WKU
Доп.точки доступа:
Abdilda, N. Sh.
Bayeshov, A.B.
13.
Подробнее
24
B14
Baeshov, A. B.
Synthesis of thallium sulphate in a sulfuric acid solution at polarization by current. [Текст] / A. B. Baeshov, E. Zh. Tuleshova, G.T. Sarbayeva, M. A. Ozler, M. T. Sarbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 47-54
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
potentiodynamic polarization curves -- electrochemical behavior -- thallium -- sulfuric acid -- current density
Аннотация: In this work, the kinetics of electrochemical oxidation-reduction of thallium in aqueous solutions of sulfuric acid is studied by potentiometry. To characterize the mechanism of thallium electrooxidation, the following parameters were calculated: the order of the reaction and the effective activation energy of the process. The impact of electrolysis modes: current density, concentration and temperature of the electrolyte on the dimensional charac-teristics of the obtained thallium (I) sulfate was investigated.
Держатели документа:
WKU
Доп.точки доступа:
Tuleshova, E. Zh.
Sarbayeva, G.T.
Ozler, M. A.
Sarbayeva, M.T.
B14
Baeshov, A. B.
Synthesis of thallium sulphate in a sulfuric acid solution at polarization by current. [Текст] / A. B. Baeshov, E. Zh. Tuleshova, G.T. Sarbayeva, M. A. Ozler, M. T. Sarbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 47-54
Рубрики: chemistry
Кл.слова (ненормированные):
potentiodynamic polarization curves -- electrochemical behavior -- thallium -- sulfuric acid -- current density
Аннотация: In this work, the kinetics of electrochemical oxidation-reduction of thallium in aqueous solutions of sulfuric acid is studied by potentiometry. To characterize the mechanism of thallium electrooxidation, the following parameters were calculated: the order of the reaction and the effective activation energy of the process. The impact of electrolysis modes: current density, concentration and temperature of the electrolyte on the dimensional charac-teristics of the obtained thallium (I) sulfate was investigated.
Держатели документа:
WKU
Доп.точки доступа:
Tuleshova, E. Zh.
Sarbayeva, G.T.
Ozler, M. A.
Sarbayeva, M.T.
14.
Подробнее
24
M96
Murzakassymova, N. C.
Modified sorbents and their application for extraction of metal ions. [Текст] / N. C. Murzakassymova, N. A. Bektenov, M. A. Gavrilenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 75-79
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
coal -- sorbents -- modification -- sorption isotherm -- sorbent capacity -- oleum
Аннотация: The data on accumulated mining waste in the territory of Kazakhstan are presented. Their processing has become very important in our time. The structure of surface-modified carbon materials with a grafted layer is given. New modified carbon sorbents were obtained, oleum was used as a modifying agent. It was revealed that the capacitive characteristics of the modified sorbent are significantly higher than that of the original one, which will make it possible to more efficiently extract the metal ion from wastewater and technogenic formations. Sorption is an effective method of extracting valuable components from wastewater and man-made formations. This method allows you to recover valuable substances with a high degree of wastewater treatment, which can be purified to the maximum permissible concentration of pollutants and then used in technological processes or in recycling water supply systems. Processing involves ores characterized by a low content of valuable components, fine dissemination and similar technological properties of minerals. The existing technologies for the development of minerals make it possible to use only a small part of the valuable mineral mass extracted from the subsoil, and the rest forms waste, which, as it accumulates and is stored, becomes one of the most significant factors of anthropogenic changes in the environment.
Держатели документа:
WKU
Доп.точки доступа:
Bektenov, N. A.
Gavrilenko, M. A.
M96
Murzakassymova, N. C.
Modified sorbents and their application for extraction of metal ions. [Текст] / N. C. Murzakassymova, N. A. Bektenov, M. A. Gavrilenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 75-79
Рубрики: chemistry
Кл.слова (ненормированные):
coal -- sorbents -- modification -- sorption isotherm -- sorbent capacity -- oleum
Аннотация: The data on accumulated mining waste in the territory of Kazakhstan are presented. Their processing has become very important in our time. The structure of surface-modified carbon materials with a grafted layer is given. New modified carbon sorbents were obtained, oleum was used as a modifying agent. It was revealed that the capacitive characteristics of the modified sorbent are significantly higher than that of the original one, which will make it possible to more efficiently extract the metal ion from wastewater and technogenic formations. Sorption is an effective method of extracting valuable components from wastewater and man-made formations. This method allows you to recover valuable substances with a high degree of wastewater treatment, which can be purified to the maximum permissible concentration of pollutants and then used in technological processes or in recycling water supply systems. Processing involves ores characterized by a low content of valuable components, fine dissemination and similar technological properties of minerals. The existing technologies for the development of minerals make it possible to use only a small part of the valuable mineral mass extracted from the subsoil, and the rest forms waste, which, as it accumulates and is stored, becomes one of the most significant factors of anthropogenic changes in the environment.
Держатели документа:
WKU
Доп.точки доступа:
Bektenov, N. A.
Gavrilenko, M. A.
15.
Подробнее
24
K21
Karmanovskaya, N. V.
Public environmental monitoring of the state of snowpack in norilsk. [Текст] / N. V. Karmanovskaya, O. V. Nosova, A. V. Kaverzin // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 95-103
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
precipitation -- industrial area -- melt water -- chemical characteristics
Аннотация: It is considered that Norilsk ranks second in terms of atmospheric contamination. Industrial enterprises annually emit large amounts of sulphur dioxide, phenols, and heavy metal particles. The city is located within the Far North and is distinguished by the harsh climate of the subarctic type. The snow cover can lie from 244 to 277 days. Snow is a good sorbent; therefore, the snow cover accumulates solid and gaseous pollutants that enter it from the atmosphere with precipitation or are absorbed from it. The purpose of this study was to analyse the snow cover in the Norilsk industrial region and assess the state of atmospheric air in the winter. To achieve this goal, it is necessary to solve the following tasks: conduct a literature review on a given topic; take samples of snow in various industrial districts of Norilsk; study the dependence of the qualitative characteristics of snow on the sampling site; draw conclusions on the quality of snowpack in different areas of the industrial districts of Norilsk. In the course of the study, the following methods were used: organoleptic, visual, methods for determining water transparency, titrimetric analysis, etc. Heavy metal ions and sulphate ions were not detected in the thawed snow, so no industrial gas pollution was noted in the residential area. Most of the particulate contamination was caused by slagging of roads to improve vehicle traction.
Держатели документа:
WKU
Доп.точки доступа:
Nosova, O. V.
Kaverzin, A. V.
K21
Karmanovskaya, N. V.
Public environmental monitoring of the state of snowpack in norilsk. [Текст] / N. V. Karmanovskaya, O. V. Nosova, A. V. Kaverzin // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 95-103
Рубрики: chemistry
Кл.слова (ненормированные):
precipitation -- industrial area -- melt water -- chemical characteristics
Аннотация: It is considered that Norilsk ranks second in terms of atmospheric contamination. Industrial enterprises annually emit large amounts of sulphur dioxide, phenols, and heavy metal particles. The city is located within the Far North and is distinguished by the harsh climate of the subarctic type. The snow cover can lie from 244 to 277 days. Snow is a good sorbent; therefore, the snow cover accumulates solid and gaseous pollutants that enter it from the atmosphere with precipitation or are absorbed from it. The purpose of this study was to analyse the snow cover in the Norilsk industrial region and assess the state of atmospheric air in the winter. To achieve this goal, it is necessary to solve the following tasks: conduct a literature review on a given topic; take samples of snow in various industrial districts of Norilsk; study the dependence of the qualitative characteristics of snow on the sampling site; draw conclusions on the quality of snowpack in different areas of the industrial districts of Norilsk. In the course of the study, the following methods were used: organoleptic, visual, methods for determining water transparency, titrimetric analysis, etc. Heavy metal ions and sulphate ions were not detected in the thawed snow, so no industrial gas pollution was noted in the residential area. Most of the particulate contamination was caused by slagging of roads to improve vehicle traction.
Держатели документа:
WKU
Доп.точки доступа:
Nosova, O. V.
Kaverzin, A. V.
16.
Подробнее
24
A99
Azimbayeva, G. E.
Gas Chromatographic analysis of the chemical composition of ethyl alcohol obtained from plants of the genus asteraceae. [Текст] / G. E. Azimbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 6-13
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
Ethyl alcohol -- plants of the genus Asteraceae -- gas chromatographic method -- chromatogram -- chemical composition
Аннотация: The article discusses the methods of obtaining and application of ethyl alcohol. The results of the analysis of the chemical composition of ethyl alcohol obtained from plants of the genus Asteraceae are presented. As a result of the study, alcohols were obtained in different concentrations. The chemical composition of ethyl alcohol was determined by gas chromatography. The impurity composition of ethyl alcohol obtained from various types of raw materials is also shown.
Держатели документа:
WKU
Доп.точки доступа:
Kamysbayeva, A.K.
Bakibaev, Abdigali
A99
Azimbayeva, G. E.
Gas Chromatographic analysis of the chemical composition of ethyl alcohol obtained from plants of the genus asteraceae. [Текст] / G. E. Azimbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 6-13
Рубрики: chemistry
Кл.слова (ненормированные):
Ethyl alcohol -- plants of the genus Asteraceae -- gas chromatographic method -- chromatogram -- chemical composition
Аннотация: The article discusses the methods of obtaining and application of ethyl alcohol. The results of the analysis of the chemical composition of ethyl alcohol obtained from plants of the genus Asteraceae are presented. As a result of the study, alcohols were obtained in different concentrations. The chemical composition of ethyl alcohol was determined by gas chromatography. The impurity composition of ethyl alcohol obtained from various types of raw materials is also shown.
Держатели документа:
WKU
Доп.точки доступа:
Kamysbayeva, A.K.
Bakibaev, Abdigali
17.
Подробнее
24
A67
Appazov, N. O.
Rice straw and husk oil sludge for processing through the use of lignosulfonate as a binder with activarted charcoal. [Текст] / N. O. Appazov, B. M. Diyarova, B. M. Bazarbayev, T. Assylbekkyzy [et al.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 65-71
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
activated carbon -- rice husk -- rice straw -- oil sludge -- lignosulfonate -- carbonization -- activation -- briquettes
Аннотация: This article examines the effect of lignosulfonate binding of rice waste to oil waste to obtain activated carbon. Lignosulfonate was added to the mixture to produce briquetted activated carbon by processing rice residue (husk and straw) and oil sludge together.
Держатели документа:
WKU
Доп.точки доступа:
Diyarova, B. M.
Bazarbayev, B. M.
Assylbekkyzy, T.
Kanzhar, S. A.
Dzhiembaev , B. Zh.
A67
Appazov, N. O.
Rice straw and husk oil sludge for processing through the use of lignosulfonate as a binder with activarted charcoal. [Текст] / N. O. Appazov, B. M. Diyarova, B. M. Bazarbayev, T. Assylbekkyzy [et al.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 65-71
Рубрики: chemistry
Кл.слова (ненормированные):
activated carbon -- rice husk -- rice straw -- oil sludge -- lignosulfonate -- carbonization -- activation -- briquettes
Аннотация: This article examines the effect of lignosulfonate binding of rice waste to oil waste to obtain activated carbon. Lignosulfonate was added to the mixture to produce briquetted activated carbon by processing rice residue (husk and straw) and oil sludge together.
Держатели документа:
WKU
Доп.точки доступа:
Diyarova, B. M.
Bazarbayev, B. M.
Assylbekkyzy, T.
Kanzhar, S. A.
Dzhiembaev , B. Zh.
18.
Подробнее
24
I-54
Ilyassov, A. E.
Investigation of the sorption characteristics of activated carbons. [Текст] / A. E. Ilyassov, A.О. Baikonurova, B. N. Surimbayev // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 105-109
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
activated carbon -- sorption -- sorption capacity of coal -- sorbent -- gold
Аннотация: The article presents the results of a comparison of the sorption characteristics for gold of crushed activated carbon of the foreign Haycarb brand, obtained from expensive raw materials - coconut shells, and crushed activated carbon of the domestic Shubarkol brand, obtained from relatively cheap raw materials - low-ash coking coal. The activated carbon Shubarkol crushed to a class of -3.6+1.0 mm, was produced in Kazakhstan from coking coal by Shubarkolkomir JSC.
Держатели документа:
WKU
Доп.точки доступа:
Baikonurova, A.О.
Surimbayev, B.N.
I-54
Ilyassov, A. E.
Investigation of the sorption characteristics of activated carbons. [Текст] / A. E. Ilyassov, A.О. Baikonurova, B. N. Surimbayev // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 105-109
Рубрики: chemistry
Кл.слова (ненормированные):
activated carbon -- sorption -- sorption capacity of coal -- sorbent -- gold
Аннотация: The article presents the results of a comparison of the sorption characteristics for gold of crushed activated carbon of the foreign Haycarb brand, obtained from expensive raw materials - coconut shells, and crushed activated carbon of the domestic Shubarkol brand, obtained from relatively cheap raw materials - low-ash coking coal. The activated carbon Shubarkol crushed to a class of -3.6+1.0 mm, was produced in Kazakhstan from coking coal by Shubarkolkomir JSC.
Держатели документа:
WKU
Доп.точки доступа:
Baikonurova, A.О.
Surimbayev, B.N.
19.
Подробнее
24
I-53
Ikhsanov, Y. S.
Amino acid and vitamin composition of crataegus orientalis pall. [Текст] / Y. S. Ikhsanov, K. M. Kusainova, G. Y. Tasmagambetova, N. T. Andasova, Y. A. Litvinenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 149-154
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
Crataegus -- Crataegus orientalis Pall -- amino acids -- vitamins -- SFE extraction
Аннотация: This article examines the study of the quantitative composition of amino acids and vitamins in the fruits of the species of the genus Crataegus widespread in Kazakhstan in a supercritical extract isolated and the fruits of the Crataegus orientalis Pall plant, in order to establish the possibility of using and with subsequent cultivation of the selected species.
Держатели документа:
WKU
Доп.точки доступа:
Kusainova, K. M.
Tasmagambetova, G. Y.
Andasova, N. T.
Litvinenko, Y. A.
I-53
Ikhsanov, Y. S.
Amino acid and vitamin composition of crataegus orientalis pall. [Текст] / Y. S. Ikhsanov, K. M. Kusainova, G. Y. Tasmagambetova, N. T. Andasova, Y. A. Litvinenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 149-154
Рубрики: chemistry
Кл.слова (ненормированные):
Crataegus -- Crataegus orientalis Pall -- amino acids -- vitamins -- SFE extraction
Аннотация: This article examines the study of the quantitative composition of amino acids and vitamins in the fruits of the species of the genus Crataegus widespread in Kazakhstan in a supercritical extract isolated and the fruits of the Crataegus orientalis Pall plant, in order to establish the possibility of using and with subsequent cultivation of the selected species.
Держатели документа:
WKU
Доп.точки доступа:
Kusainova, K. M.
Tasmagambetova, G. Y.
Andasova, N. T.
Litvinenko, Y. A.
20.
Подробнее
24
K17
Кairbekov, Zh. К.
Physicochemical and antioxidant properties of humic acids of low-mineralized peloids of the Tuzkol deposit. [Текст] / Zh. К. Кairbekov, I. M. Jeldybayeva, D. Z. Аbilmazhinova, S. M. Suimbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 48-53
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
Low-mineralized sludge sulphide mud (peloids) -- humic -- fulvic -- hymatomelanic -- humic acids -- antioxidant activity
Аннотация: As a result of studies it was found that the peloids of the deposit of Tuzkol Lake (Republic of Kazakhstan) are high quality medium-sulfide, weakly alkaline sludge muds. It was found that peloid-derived humic acid contains 49.63 % oxygen, 22.37% carbon, 9.65 % silicon and 6.26% calcium; it also contains Na, Mg, Al, Fe and an insignificant amount of S, Cl, K, F. Electron microscopy and IR spectroscopy analysis of the molecular structure of humic substances of peloids indicated that their macromolecule consists of framework olefinic and aromatic fragments with a substantial proportion of unoxidized aliphatic groups, as well as aromatic structures containing carboxyl groups. The findings of amperometric detection of the antioxidant properties of humic acids suggest that they have antioxidant activity, which will make it possible to use them as a biologically active substance for medicines.
Держатели документа:
WKU
Доп.точки доступа:
Jeldybayeva, I.M.
Аbilmazhinova, D.Z.
Suimbayeva, S.M.
K17
Кairbekov, Zh. К.
Physicochemical and antioxidant properties of humic acids of low-mineralized peloids of the Tuzkol deposit. [Текст] / Zh. К. Кairbekov, I. M. Jeldybayeva, D. Z. Аbilmazhinova, S. M. Suimbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 48-53
Рубрики: chemistry
Кл.слова (ненормированные):
Low-mineralized sludge sulphide mud (peloids) -- humic -- fulvic -- hymatomelanic -- humic acids -- antioxidant activity
Аннотация: As a result of studies it was found that the peloids of the deposit of Tuzkol Lake (Republic of Kazakhstan) are high quality medium-sulfide, weakly alkaline sludge muds. It was found that peloid-derived humic acid contains 49.63 % oxygen, 22.37% carbon, 9.65 % silicon and 6.26% calcium; it also contains Na, Mg, Al, Fe and an insignificant amount of S, Cl, K, F. Electron microscopy and IR spectroscopy analysis of the molecular structure of humic substances of peloids indicated that their macromolecule consists of framework olefinic and aromatic fragments with a substantial proportion of unoxidized aliphatic groups, as well as aromatic structures containing carboxyl groups. The findings of amperometric detection of the antioxidant properties of humic acids suggest that they have antioxidant activity, which will make it possible to use them as a biologically active substance for medicines.
Держатели документа:
WKU
Доп.точки доступа:
Jeldybayeva, I.M.
Аbilmazhinova, D.Z.
Suimbayeva, S.M.
Страница 2, Результатов: 28