База данных: Статьи
Страница 2, Результатов: 27
Отмеченные записи: 0
11.
Подробнее
35
B15
Bagova, Z.
Analysis and prospective utilization of technogenic slag waste from a lead plant. [Текст] / Z. Bagova, K. Zhantasov, G. Turebekova, B. Sapargaliyeva, Javier Rodrigo-Iiarri // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 22-28
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
waste -- lead-zinc waste -- secondary raw materials -- non-ferrous metals -- valuable components -- waste processing -- waste disposal -- low-waste and non-waste technologies
Аннотация: The article presents the analysis and results of the study of technogenic slag waste of lead-zinc production. Slags of lead-zinc production contain a large number of toxic compounds: lead, zinc, osmium, cadmium, which are dangerous sources of environmental pollution. Due to the open storage of slags, it was found that the maximum permissible concentrations of lead were exceeded. Utilization of man-made slag waste is of great importance for reducing the negative impact on the safety of life and improving the environmental situation in the region. At the same time, slags are valuable raw materials containing compounds of non-ferrous and rare-earth metals.
Держатели документа:
WKU
Доп.точки доступа:
Zhantasov, K.
Turebekova, G.
Sapargaliyeva, B.
Rodrigo-Iiarri, Javier
B15
Bagova, Z.
Analysis and prospective utilization of technogenic slag waste from a lead plant. [Текст] / Z. Bagova, K. Zhantasov, G. Turebekova, B. Sapargaliyeva, Javier Rodrigo-Iiarri // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 22-28
Рубрики: chemical Technology
Кл.слова (ненормированные):
waste -- lead-zinc waste -- secondary raw materials -- non-ferrous metals -- valuable components -- waste processing -- waste disposal -- low-waste and non-waste technologies
Аннотация: The article presents the analysis and results of the study of technogenic slag waste of lead-zinc production. Slags of lead-zinc production contain a large number of toxic compounds: lead, zinc, osmium, cadmium, which are dangerous sources of environmental pollution. Due to the open storage of slags, it was found that the maximum permissible concentrations of lead were exceeded. Utilization of man-made slag waste is of great importance for reducing the negative impact on the safety of life and improving the environmental situation in the region. At the same time, slags are valuable raw materials containing compounds of non-ferrous and rare-earth metals.
Держатели документа:
WKU
Доп.точки доступа:
Zhantasov, K.
Turebekova, G.
Sapargaliyeva, B.
Rodrigo-Iiarri, Javier
12.
Подробнее
35
K17
Kalmakhanova, M. S.
New adsorbents developed from netural clays to remove ni (II) from wastewater. [Текст] / M. S. Kalmakhanova, А. Amantaikyzy, J. L. Diaz de Tuesta, G. A. Seitbekova [et al.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 45-52
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
clay -- adsorption -- nickel -- heavy metal -- wastewater -- pillared clay
Аннотация: This work deals with the development of materials based on natural clays and on pillared clays and further application in the the adsorption of Ni (II), used as model pollutant, from aqueous solution. The starting natural clay (montmorillonite) was obtained in a deposit of Kazakhstan (Asa), and two additional samples were prepared by treatment of the natural clay with acid and by pillarization with Fe2+and Zn2+.
Держатели документа:
WKU
Доп.точки доступа:
Amantaikyzy, А.
Diaz de Tuesta, J. L.
Seitbekova, G. A.
Darmenbaeva, A. S.
Reimbaeva, S.
K17
Kalmakhanova, M. S.
New adsorbents developed from netural clays to remove ni (II) from wastewater. [Текст] / M. S. Kalmakhanova, А. Amantaikyzy, J. L. Diaz de Tuesta, G. A. Seitbekova [et al.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 45-52
Рубрики: chemical Technology
Кл.слова (ненормированные):
clay -- adsorption -- nickel -- heavy metal -- wastewater -- pillared clay
Аннотация: This work deals with the development of materials based on natural clays and on pillared clays and further application in the the adsorption of Ni (II), used as model pollutant, from aqueous solution. The starting natural clay (montmorillonite) was obtained in a deposit of Kazakhstan (Asa), and two additional samples were prepared by treatment of the natural clay with acid and by pillarization with Fe2+and Zn2+.
Держатели документа:
WKU
Доп.точки доступа:
Amantaikyzy, А.
Diaz de Tuesta, J. L.
Seitbekova, G. A.
Darmenbaeva, A. S.
Reimbaeva, S.
13.
Подробнее
35
D99
Dzhumadullaeva, S. A.
The kinetics of selective hydrazinolysis of maleic acid on the acid catalyst. [Текст] / S. A. Dzhumadullaeva, A. B. Bayeshov, A. V. Kolesnikov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 53-57
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
maleic acid -- hydrazinolysis -- hydrazide -- catalyst
Аннотация: For the first time, kinetics and the mechanism of the reaction of hydrazinolysis of maleic acid in the presence of cation exchanger resin KU-2-8 in H-form have been studied. The experiments were carried out in a static system in a thermostat glass reactor. It was found that cation exchanger shows high catalytic activity in the studied process - maleic acid conversion was 93%, and maleic hydrazide yield was 90%. The conversion selectivity of maleic acid to maleic hydrazide was 97,8%. The reaction rate was determined from the accumulation of maleic hydrazide. The apparent reaction rate constant (k) was calculated from the second-order reaction rate equation. The effect of initial concentrations of maleic acid and hydrazine hydrate, the temperature on the reaction rate was studied. The first order of maleic acid and hydrazine hydrate is determined. Activation energy of the process found from the Arrhenius dependence is 32,1 kJ/mol. On the basis of kinetic and IR spectroscopic methods, a probable reaction mechanism involving polymer-bound hydrogen ions is proposed.
Держатели документа:
WKU
Доп.точки доступа:
Bayeshov, A.B.
Kolesnikov, A.V.
D99
Dzhumadullaeva, S. A.
The kinetics of selective hydrazinolysis of maleic acid on the acid catalyst. [Текст] / S. A. Dzhumadullaeva, A. B. Bayeshov, A. V. Kolesnikov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 53-57
Рубрики: chemical Technology
Кл.слова (ненормированные):
maleic acid -- hydrazinolysis -- hydrazide -- catalyst
Аннотация: For the first time, kinetics and the mechanism of the reaction of hydrazinolysis of maleic acid in the presence of cation exchanger resin KU-2-8 in H-form have been studied. The experiments were carried out in a static system in a thermostat glass reactor. It was found that cation exchanger shows high catalytic activity in the studied process - maleic acid conversion was 93%, and maleic hydrazide yield was 90%. The conversion selectivity of maleic acid to maleic hydrazide was 97,8%. The reaction rate was determined from the accumulation of maleic hydrazide. The apparent reaction rate constant (k) was calculated from the second-order reaction rate equation. The effect of initial concentrations of maleic acid and hydrazine hydrate, the temperature on the reaction rate was studied. The first order of maleic acid and hydrazine hydrate is determined. Activation energy of the process found from the Arrhenius dependence is 32,1 kJ/mol. On the basis of kinetic and IR spectroscopic methods, a probable reaction mechanism involving polymer-bound hydrogen ions is proposed.
Держатели документа:
WKU
Доп.точки доступа:
Bayeshov, A.B.
Kolesnikov, A.V.
14.
Подробнее
35
K17
Kairbekov, Zh. K.
Investigation of the catalytic and isomerization activity of multi-component skeletal nickel catalysts in the hydrogenation of hexene -1. [Текст] / Zh. K. Kairbekov, S. M. Suimbayeva, I. M. Jeldybayeva, E. T. Yermoldina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - p. 58-64
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
catalyst -- hydrogenation -- hexеne-1 -- skeletal nickel -- activity -- selectivity -- migration -- alloy
Аннотация: In this work, the effect of the amount of catalyst, modifying additives, and the phase composition of the alloys on the catalytic and isomerizing activity of skeletal in the hydrogenation reaction of hexane-1 is investigated.
Держатели документа:
WKU
Доп.точки доступа:
Suimbayeva, S. M.
Jeldybayeva, I. M.
Yermoldina, E. T.
K17
Kairbekov, Zh. K.
Investigation of the catalytic and isomerization activity of multi-component skeletal nickel catalysts in the hydrogenation of hexene -1. [Текст] / Zh. K. Kairbekov, S. M. Suimbayeva, I. M. Jeldybayeva, E. T. Yermoldina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - p. 58-64
Рубрики: chemical Technology
Кл.слова (ненормированные):
catalyst -- hydrogenation -- hexеne-1 -- skeletal nickel -- activity -- selectivity -- migration -- alloy
Аннотация: In this work, the effect of the amount of catalyst, modifying additives, and the phase composition of the alloys on the catalytic and isomerizing activity of skeletal in the hydrogenation reaction of hexane-1 is investigated.
Держатели документа:
WKU
Доп.точки доступа:
Suimbayeva, S. M.
Jeldybayeva, I. M.
Yermoldina, E. T.
15.
Подробнее
35
Y45
Yermagambet, B. T.
Production of carbon nanofibers based on coal tar and polyacryonitrile by electrospinning method. [Текст] / B. T. Yermagambet, M. K. Kazankapova, A. T. Nauryzbayeva, Zh. M. Kassenova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 72-80
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
carbon nanofiber -- coal tar -- polyacrylonitrile -- electrospinning -- oxidation -- carbonization
Аннотация: The article presents experiments on obtaining composite fibers based on Shubarkol coal tar (CT) and polycarlonitrile (PAN) by electrospinning in a laboratory setup. As a result of energy dispersive X-ray spectroscopy and SEM microscopy, the elemental composition (C-85.83%) and the diameter of the carbon fiber were determined, which ranged from 89.0 nm to 449.8 nm. The resulting CNF was subjected to oxidation in air at 300 °C, the holding time was 1 hour, after which the carbonization process was carried out at 800 °C, followed by cooling to room temperature.
Держатели документа:
WKU
Доп.точки доступа:
Kazankapova, M.K.
Nauryzbayeva, A.T.
Kassenova, Zh.M.
Y45
Yermagambet, B. T.
Production of carbon nanofibers based on coal tar and polyacryonitrile by electrospinning method. [Текст] / B. T. Yermagambet, M. K. Kazankapova, A. T. Nauryzbayeva, Zh. M. Kassenova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 72-80
Рубрики: chemical Technology
Кл.слова (ненормированные):
carbon nanofiber -- coal tar -- polyacrylonitrile -- electrospinning -- oxidation -- carbonization
Аннотация: The article presents experiments on obtaining composite fibers based on Shubarkol coal tar (CT) and polycarlonitrile (PAN) by electrospinning in a laboratory setup. As a result of energy dispersive X-ray spectroscopy and SEM microscopy, the elemental composition (C-85.83%) and the diameter of the carbon fiber were determined, which ranged from 89.0 nm to 449.8 nm. The resulting CNF was subjected to oxidation in air at 300 °C, the holding time was 1 hour, after which the carbonization process was carried out at 800 °C, followed by cooling to room temperature.
Держатели документа:
WKU
Доп.точки доступа:
Kazankapova, M.K.
Nauryzbayeva, A.T.
Kassenova, Zh.M.
16.
Подробнее
35
Z63
Zhantassov, K.
Development of technology for extraction of lead and zinc oxides from dust and slags during the utilization of lead plant waste. [Текст] / K. Zhantassov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 81-85
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
waste -- lead waste -- oxic compounds -- lead and zinc compounds -- environmental pollution -- toxic waste processing -- waste disposal
Аннотация: The article proposes methods for the extraction of lead and zinc from slag waste and selects the optimal method for the selective extraction of zinc and lead oxides from dust and slags of lead production. The proposed technology of continuous carbon-free selective extraction of zinc and lead from the dust of electric steelmaking production allows the use of lead production slag, which is fed into a rotating drum furnace in two oppositely directed streams. During the movement of lead slag in the furnace drum and the burning of the torch, lead and zinc are more completely extracted from the dust-like material, where the transporting object is compressed air, and the purified flue gas after the gas is further purified by means of a smoke pump is released into the atmosphere.
Держатели документа:
WKU
Доп.точки доступа:
Bagova, Z.
Turebekova, G.
Sapargaliyeva, B.
Pusurmanova, G.
Z63
Zhantassov, K.
Development of technology for extraction of lead and zinc oxides from dust and slags during the utilization of lead plant waste. [Текст] / K. Zhantassov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 81-85
Рубрики: chemical Technology
Кл.слова (ненормированные):
waste -- lead waste -- oxic compounds -- lead and zinc compounds -- environmental pollution -- toxic waste processing -- waste disposal
Аннотация: The article proposes methods for the extraction of lead and zinc from slag waste and selects the optimal method for the selective extraction of zinc and lead oxides from dust and slags of lead production. The proposed technology of continuous carbon-free selective extraction of zinc and lead from the dust of electric steelmaking production allows the use of lead production slag, which is fed into a rotating drum furnace in two oppositely directed streams. During the movement of lead slag in the furnace drum and the burning of the torch, lead and zinc are more completely extracted from the dust-like material, where the transporting object is compressed air, and the purified flue gas after the gas is further purified by means of a smoke pump is released into the atmosphere.
Держатели документа:
WKU
Доп.точки доступа:
Bagova, Z.
Turebekova, G.
Sapargaliyeva, B.
Pusurmanova, G.
17.
Подробнее
35
A92
Augaliev, D. B.
Oxidative dimerization of methane to C2 hydrocarbons. [Текст] / D. B. Augaliev, M. K. Erkibaeva, A. O. Aidarova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 18-24
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
ODM reaction -- C2 hydrocarbons -- SHS method -- temperature of reaction
Аннотация: The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce-20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction.
Держатели документа:
WKU
Доп.точки доступа:
Erkibaeva, M.K.
Aidarova, A.O.
Tungatarova, S.А.
Baizhumanova, T.S.
A92
Augaliev, D. B.
Oxidative dimerization of methane to C2 hydrocarbons. [Текст] / D. B. Augaliev, M. K. Erkibaeva, A. O. Aidarova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 18-24
Рубрики: chemical Technology
Кл.слова (ненормированные):
ODM reaction -- C2 hydrocarbons -- SHS method -- temperature of reaction
Аннотация: The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce-20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction.
Держатели документа:
WKU
Доп.точки доступа:
Erkibaeva, M.K.
Aidarova, A.O.
Tungatarova, S.А.
Baizhumanova, T.S.
18.
Подробнее
35
J21
Jalmakhanbetova, R.I.
Calculate the standard enthalpies of combustion , formation and melting of the complex roseofungin with a-, B- and y- cyclodextrin. [Текст] / R.I. Jalmakhanbetova, Ye. M. Suleimen, B. K. Kasenov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 44-47
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
roseofungin -- cyclodextrin -- standard enthalpy of combustion -- standard enthalpy of formation -- enthalpy of melting of a complex
Аннотация: One of the most important quantities in chemical thermodynamics and thermochemistry is the enthalpy of combustion. Of the currently existing methods for calculating the heat of combustion of natural and synthetic organic compounds, the most acceptable and correct in our case was the Karash method. In this study, the standard enthalpy of combustion, the standard enthalpy of formation, and the melting enthalpy of the antibiotic roseofungin and its cyclodextrin derivatives were calculated. As a result of the study, the thermodynamic constants of the standard enthalpies of combustion, standard enthalpies of formation, and the enthalpies of melting of the above compounds were calculated, which are of interest for physicochemical modeling of processes with their participation, serve as initial information arrays for loading into fundamental thermodynamic data banks and reference books, and is also important for standardization and certification of these complexes. It should be noted that the presence of a large number of hydroxyl groups in the structures of the studied complexes allows them to be attributed to polar compounds.
Держатели документа:
WKU
Доп.точки доступа:
Suleimen, Ye.M.
Kasenov, B.K.
J21
Jalmakhanbetova, R.I.
Calculate the standard enthalpies of combustion , formation and melting of the complex roseofungin with a-, B- and y- cyclodextrin. [Текст] / R.I. Jalmakhanbetova, Ye. M. Suleimen, B. K. Kasenov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 44-47
Рубрики: chemical Technology
Кл.слова (ненормированные):
roseofungin -- cyclodextrin -- standard enthalpy of combustion -- standard enthalpy of formation -- enthalpy of melting of a complex
Аннотация: One of the most important quantities in chemical thermodynamics and thermochemistry is the enthalpy of combustion. Of the currently existing methods for calculating the heat of combustion of natural and synthetic organic compounds, the most acceptable and correct in our case was the Karash method. In this study, the standard enthalpy of combustion, the standard enthalpy of formation, and the melting enthalpy of the antibiotic roseofungin and its cyclodextrin derivatives were calculated. As a result of the study, the thermodynamic constants of the standard enthalpies of combustion, standard enthalpies of formation, and the enthalpies of melting of the above compounds were calculated, which are of interest for physicochemical modeling of processes with their participation, serve as initial information arrays for loading into fundamental thermodynamic data banks and reference books, and is also important for standardization and certification of these complexes. It should be noted that the presence of a large number of hydroxyl groups in the structures of the studied complexes allows them to be attributed to polar compounds.
Держатели документа:
WKU
Доп.точки доступа:
Suleimen, Ye.M.
Kasenov, B.K.
19.
Подробнее
35
R18
Rakhimberlinova, Zh. B.
Chemical activation of the surface of the burnt rock by various modifiers. [Текст] / Zh. B. Rakhimberlinova, I. V. Kulakov, A.Zh. Alimzhanova, M. М. Mussirepov, N. E. Nakypbekova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 81-86
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
oxidized coals -- humic acids -- inorganic surfaces -- burnt rock -- host rock -- modifiers
Аннотация: This article presents the results of experimental studies of the process of grafting humic acids and their functional derivatives on modified and unmodified surfaces of burnt rock. It is shown that the inoculation of humic acids on inorganic carriers is more successful with the preliminary activation of the surface of burnt rocks.
Держатели документа:
WKU
Доп.точки доступа:
Kulakov, I.V.
Alimzhanova, A.Zh.
Mussirepov, M.М.
Nakypbekova, N.E.
R18
Rakhimberlinova, Zh. B.
Chemical activation of the surface of the burnt rock by various modifiers. [Текст] / Zh. B. Rakhimberlinova, I. V. Kulakov, A.Zh. Alimzhanova, M. М. Mussirepov, N. E. Nakypbekova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 81-86
Рубрики: chemical Technology
Кл.слова (ненормированные):
oxidized coals -- humic acids -- inorganic surfaces -- burnt rock -- host rock -- modifiers
Аннотация: This article presents the results of experimental studies of the process of grafting humic acids and their functional derivatives on modified and unmodified surfaces of burnt rock. It is shown that the inoculation of humic acids on inorganic carriers is more successful with the preliminary activation of the surface of burnt rocks.
Держатели документа:
WKU
Доп.точки доступа:
Kulakov, I.V.
Alimzhanova, A.Zh.
Mussirepov, M.М.
Nakypbekova, N.E.
20.
Подробнее
35
R24
Rasulov, S. R.
Development of effective catalysts for processing C3-C4 Hydrocarbons. [Текст] / S. R. Rasulov, G. R. Mustafayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 87-93
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
refinery gases -- 3-C4 hydrocarbons -- zeolite-containing catalyst -- modifiers -- reaction-regeneration cycles.
Аннотация: The aim of the article is to study the effect of preparation and activation methods of a modified zeolite-containing catalyst on the activity and stability of catalytic properties displayed by it during the conversion of C3-C4 hydrocarbons. During the experiment, the industrial cracking catalyst OMNIKAT, which is a zeolite in the sodium form, was used as the initial one. Zinc, gallium, and REE (rare earth elements) were sequentially applied to decationized samples of this catalyst by ion exchange, impregnation, and dry mechanical mixing, and the effect of these methods on the catalytic properties of the zeolite-containing catalyst was observed. As a result of a comparative analysis of the regularities of aromatization of C3-C4hydrocarbons, it was found that the mechanical mixing method is the most preferable, since it provides the best process performance.
Держатели документа:
WKU
Доп.точки доступа:
Mustafayeva, G.R.
R24
Rasulov, S. R.
Development of effective catalysts for processing C3-C4 Hydrocarbons. [Текст] / S. R. Rasulov, G. R. Mustafayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 87-93
Рубрики: chemical Technology
Кл.слова (ненормированные):
refinery gases -- 3-C4 hydrocarbons -- zeolite-containing catalyst -- modifiers -- reaction-regeneration cycles.
Аннотация: The aim of the article is to study the effect of preparation and activation methods of a modified zeolite-containing catalyst on the activity and stability of catalytic properties displayed by it during the conversion of C3-C4 hydrocarbons. During the experiment, the industrial cracking catalyst OMNIKAT, which is a zeolite in the sodium form, was used as the initial one. Zinc, gallium, and REE (rare earth elements) were sequentially applied to decationized samples of this catalyst by ion exchange, impregnation, and dry mechanical mixing, and the effect of these methods on the catalytic properties of the zeolite-containing catalyst was observed. As a result of a comparative analysis of the regularities of aromatization of C3-C4hydrocarbons, it was found that the mechanical mixing method is the most preferable, since it provides the best process performance.
Держатели документа:
WKU
Доп.точки доступа:
Mustafayeva, G.R.
Страница 2, Результатов: 27