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521.
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24
M96
Murzakassymova, N. C.
Modified sorbents and their application for extraction of metal ions. [Текст] / N. C. Murzakassymova, N. A. Bektenov, M. A. Gavrilenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 75-79
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
coal -- sorbents -- modification -- sorption isotherm -- sorbent capacity -- oleum
Аннотация: The data on accumulated mining waste in the territory of Kazakhstan are presented. Their processing has become very important in our time. The structure of surface-modified carbon materials with a grafted layer is given. New modified carbon sorbents were obtained, oleum was used as a modifying agent. It was revealed that the capacitive characteristics of the modified sorbent are significantly higher than that of the original one, which will make it possible to more efficiently extract the metal ion from wastewater and technogenic formations. Sorption is an effective method of extracting valuable components from wastewater and man-made formations. This method allows you to recover valuable substances with a high degree of wastewater treatment, which can be purified to the maximum permissible concentration of pollutants and then used in technological processes or in recycling water supply systems. Processing involves ores characterized by a low content of valuable components, fine dissemination and similar technological properties of minerals. The existing technologies for the development of minerals make it possible to use only a small part of the valuable mineral mass extracted from the subsoil, and the rest forms waste, which, as it accumulates and is stored, becomes one of the most significant factors of anthropogenic changes in the environment.
Держатели документа:
WKU
Доп.точки доступа:
Bektenov, N. A.
Gavrilenko, M. A.
M96
Murzakassymova, N. C.
Modified sorbents and their application for extraction of metal ions. [Текст] / N. C. Murzakassymova, N. A. Bektenov, M. A. Gavrilenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 75-79
Рубрики: chemistry
Кл.слова (ненормированные):
coal -- sorbents -- modification -- sorption isotherm -- sorbent capacity -- oleum
Аннотация: The data on accumulated mining waste in the territory of Kazakhstan are presented. Their processing has become very important in our time. The structure of surface-modified carbon materials with a grafted layer is given. New modified carbon sorbents were obtained, oleum was used as a modifying agent. It was revealed that the capacitive characteristics of the modified sorbent are significantly higher than that of the original one, which will make it possible to more efficiently extract the metal ion from wastewater and technogenic formations. Sorption is an effective method of extracting valuable components from wastewater and man-made formations. This method allows you to recover valuable substances with a high degree of wastewater treatment, which can be purified to the maximum permissible concentration of pollutants and then used in technological processes or in recycling water supply systems. Processing involves ores characterized by a low content of valuable components, fine dissemination and similar technological properties of minerals. The existing technologies for the development of minerals make it possible to use only a small part of the valuable mineral mass extracted from the subsoil, and the rest forms waste, which, as it accumulates and is stored, becomes one of the most significant factors of anthropogenic changes in the environment.
Держатели документа:
WKU
Доп.точки доступа:
Bektenov, N. A.
Gavrilenko, M. A.
522.
Подробнее
28
K42
Khalmurzayeva, B. A.
Biochemical indicators and application of Cyanobacteria Spirulina Microalgae in the cattle feedstuff. [Текст] / B. A. Khalmurzayeva, B. Sh. Ismailkhodjaev, K. P. Kuatbekova, R. S. Alibekov [et al.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 80-88
ББК 28
Рубрики: Biology
Кл.слова (ненормированные):
antioxidants -- biologically active substances -- cultivation -- genus -- microalgae -- phyto-cultures -- Spirulina
Аннотация: The qualitative and quantitative compositions of the valuable biologically active substances, species and strains of microalgae are related the genus of CyanobacteriaSp.platensis and Sp.labgrinthifosmis that were isolated from local nature and grown in semi-production facilities were considered. In order to adapt for mass cultivation, algae were first grown in greenhouse conditions. The algae were cultivated within 12 days. The produc-tivity in the tubular cultivator with stirring of Sp.platensis was 3.8 g / l, protein (73.0%), and Sp.laberinthiformis was 2.6 g / l of protein (63.1%). Similar studies were carried out in the open-air conditions that showed an increase in the amount of illumination causes a significant restructuring of the entire photosynthetic apparatus of algae. The accumulation of Sp.labyrinthiformis 2.7 g / l a.d.c., protein 62.21%, and Sp.platensis 4.08 g / l, protein 75.3%, were within 10 days. The content of protein and carotenes sharply increases in comparison with the greenhouse conditions. It was found that the addition of Sp.platensis suspension, as a protein-vitamin supplement for the bulls’ feedstuff, stimulates physiological processes that improves the biochemical parameters of their blood, the digestibility coefficient of nutrients by 8-9%, positive mineral balance, increases live weight gain (17.4%) and slaughter yield of the bulls (3.6%). So, the suspension of Sp.platensis is recommended for use as a protein-vitamin supplement in livestock farms that will allow having a significant economic effect in livestock farming, in average 20-25% profits per yearly.
Держатели документа:
WKU
Доп.точки доступа:
Ismailkhodjaev, B. Sh.
Kuatbekova, K. P.
Alibekov, R. S.
Makhatova, A. I.
Meimanbaeva, S. S.
K42
Khalmurzayeva, B. A.
Biochemical indicators and application of Cyanobacteria Spirulina Microalgae in the cattle feedstuff. [Текст] / B. A. Khalmurzayeva, B. Sh. Ismailkhodjaev, K. P. Kuatbekova, R. S. Alibekov [et al.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 80-88
Рубрики: Biology
Кл.слова (ненормированные):
antioxidants -- biologically active substances -- cultivation -- genus -- microalgae -- phyto-cultures -- Spirulina
Аннотация: The qualitative and quantitative compositions of the valuable biologically active substances, species and strains of microalgae are related the genus of CyanobacteriaSp.platensis and Sp.labgrinthifosmis that were isolated from local nature and grown in semi-production facilities were considered. In order to adapt for mass cultivation, algae were first grown in greenhouse conditions. The algae were cultivated within 12 days. The produc-tivity in the tubular cultivator with stirring of Sp.platensis was 3.8 g / l, protein (73.0%), and Sp.laberinthiformis was 2.6 g / l of protein (63.1%). Similar studies were carried out in the open-air conditions that showed an increase in the amount of illumination causes a significant restructuring of the entire photosynthetic apparatus of algae. The accumulation of Sp.labyrinthiformis 2.7 g / l a.d.c., protein 62.21%, and Sp.platensis 4.08 g / l, protein 75.3%, were within 10 days. The content of protein and carotenes sharply increases in comparison with the greenhouse conditions. It was found that the addition of Sp.platensis suspension, as a protein-vitamin supplement for the bulls’ feedstuff, stimulates physiological processes that improves the biochemical parameters of their blood, the digestibility coefficient of nutrients by 8-9%, positive mineral balance, increases live weight gain (17.4%) and slaughter yield of the bulls (3.6%). So, the suspension of Sp.platensis is recommended for use as a protein-vitamin supplement in livestock farms that will allow having a significant economic effect in livestock farming, in average 20-25% profits per yearly.
Держатели документа:
WKU
Доп.точки доступа:
Ismailkhodjaev, B. Sh.
Kuatbekova, K. P.
Alibekov, R. S.
Makhatova, A. I.
Meimanbaeva, S. S.
523.
Подробнее
24
K21
Karmanovskaya, N. V.
Public environmental monitoring of the state of snowpack in norilsk. [Текст] / N. V. Karmanovskaya, O. V. Nosova, A. V. Kaverzin // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 95-103
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
precipitation -- industrial area -- melt water -- chemical characteristics
Аннотация: It is considered that Norilsk ranks second in terms of atmospheric contamination. Industrial enterprises annually emit large amounts of sulphur dioxide, phenols, and heavy metal particles. The city is located within the Far North and is distinguished by the harsh climate of the subarctic type. The snow cover can lie from 244 to 277 days. Snow is a good sorbent; therefore, the snow cover accumulates solid and gaseous pollutants that enter it from the atmosphere with precipitation or are absorbed from it. The purpose of this study was to analyse the snow cover in the Norilsk industrial region and assess the state of atmospheric air in the winter. To achieve this goal, it is necessary to solve the following tasks: conduct a literature review on a given topic; take samples of snow in various industrial districts of Norilsk; study the dependence of the qualitative characteristics of snow on the sampling site; draw conclusions on the quality of snowpack in different areas of the industrial districts of Norilsk. In the course of the study, the following methods were used: organoleptic, visual, methods for determining water transparency, titrimetric analysis, etc. Heavy metal ions and sulphate ions were not detected in the thawed snow, so no industrial gas pollution was noted in the residential area. Most of the particulate contamination was caused by slagging of roads to improve vehicle traction.
Держатели документа:
WKU
Доп.точки доступа:
Nosova, O. V.
Kaverzin, A. V.
K21
Karmanovskaya, N. V.
Public environmental monitoring of the state of snowpack in norilsk. [Текст] / N. V. Karmanovskaya, O. V. Nosova, A. V. Kaverzin // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 95-103
Рубрики: chemistry
Кл.слова (ненормированные):
precipitation -- industrial area -- melt water -- chemical characteristics
Аннотация: It is considered that Norilsk ranks second in terms of atmospheric contamination. Industrial enterprises annually emit large amounts of sulphur dioxide, phenols, and heavy metal particles. The city is located within the Far North and is distinguished by the harsh climate of the subarctic type. The snow cover can lie from 244 to 277 days. Snow is a good sorbent; therefore, the snow cover accumulates solid and gaseous pollutants that enter it from the atmosphere with precipitation or are absorbed from it. The purpose of this study was to analyse the snow cover in the Norilsk industrial region and assess the state of atmospheric air in the winter. To achieve this goal, it is necessary to solve the following tasks: conduct a literature review on a given topic; take samples of snow in various industrial districts of Norilsk; study the dependence of the qualitative characteristics of snow on the sampling site; draw conclusions on the quality of snowpack in different areas of the industrial districts of Norilsk. In the course of the study, the following methods were used: organoleptic, visual, methods for determining water transparency, titrimetric analysis, etc. Heavy metal ions and sulphate ions were not detected in the thawed snow, so no industrial gas pollution was noted in the residential area. Most of the particulate contamination was caused by slagging of roads to improve vehicle traction.
Держатели документа:
WKU
Доп.точки доступа:
Nosova, O. V.
Kaverzin, A. V.
524.
Подробнее
35
K21
Karmanovskaya , N. V.
Public environmental monitoring of drinking water quality in the city of Norilsk. [Текст] / N. V. Karmanovskaya // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 104-111
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
ecological situation -- industrial city -- water supply -- public utilities
Аннотация: According to UN estimates, the shortage of safe drinking water can become one of the most acute and pressing problems. The specificity of this problem for Russia is not a shortage of water resources, but their pollution and ongoing degradation of water bodies. The quality of water is understood as the totality of its properties associated with the nature and concentration of impurities in the water. Water analysis is the only tool for monitoring its condition and properties. During the experiment, a team of researchers took samples of drinking water from the water supply network in various districts of the Norilsk industrial region, studied the dependence of the quality characteristics of water on the location and sampling method. Based on the findings, conclusions on the quality of drinking water were drawn. During the experiment, the authors found that in terms of organoleptic indicators, drinking water in all areas of the NIR meets the requirements of Sanitary Rules and Regulations and GOST. Taking samples at three control points of the Norilsk industrial region, it has been proven that the water is soft and its salt content is mainly due to the presence of hardness salts. Having made the necessary analyses, the authors found that the presence of microorganisms in the water supply network of the NIR is not significant, the permanganate oxidisability indicator does not exceed the requirements of Sanitary Rules and Regulations.
Держатели документа:
WKU
K21
Karmanovskaya , N. V.
Public environmental monitoring of drinking water quality in the city of Norilsk. [Текст] / N. V. Karmanovskaya // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 104-111
Рубрики: chemical Technology
Кл.слова (ненормированные):
ecological situation -- industrial city -- water supply -- public utilities
Аннотация: According to UN estimates, the shortage of safe drinking water can become one of the most acute and pressing problems. The specificity of this problem for Russia is not a shortage of water resources, but their pollution and ongoing degradation of water bodies. The quality of water is understood as the totality of its properties associated with the nature and concentration of impurities in the water. Water analysis is the only tool for monitoring its condition and properties. During the experiment, a team of researchers took samples of drinking water from the water supply network in various districts of the Norilsk industrial region, studied the dependence of the quality characteristics of water on the location and sampling method. Based on the findings, conclusions on the quality of drinking water were drawn. During the experiment, the authors found that in terms of organoleptic indicators, drinking water in all areas of the NIR meets the requirements of Sanitary Rules and Regulations and GOST. Taking samples at three control points of the Norilsk industrial region, it has been proven that the water is soft and its salt content is mainly due to the presence of hardness salts. Having made the necessary analyses, the authors found that the presence of microorganisms in the water supply network of the NIR is not significant, the permanganate oxidisability indicator does not exceed the requirements of Sanitary Rules and Regulations.
Держатели документа:
WKU
525.
Подробнее
36
S53
Shunekeyeva, А. А.
Fruit-berry fillers in the production of kazakh national fermented milk drinks. [Текст] / А. А. Shunekeyeva, M. K. Alimardanova, A. A. Majorov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 139-146
ББК 36
Рубрики: Пищевые производства
Кл.слова (ненормированные):
ayran -- ermented milk drink -- fruit and berry filler -- goat's milk -- mathematical model -- ozonisation
Аннотация: This paper offers investigation of fruit and berry fillers on the rheological properties of fermented milk drinks. The research was conducted as part of a scientific research effort. Local wild plants were used as fillers. This type of research allowed expanding the range of products at the enterprise and improving the organoleptic and nutritional properties of products. The purpose of this article is to find additional local vegetable raw materials as filler for fermented milk products. The importance of the results is that the data obtained can be used by specialists of dairy farms. During the period of coronavirus infection, when there were interruptions in the supply of raw materials, such directions it sets for future research as the development and improvement new food products by using local plant raw materials were revealed.
Держатели документа:
WKU
Доп.точки доступа:
Alimardanova, M. K.
Majorov, A. A.
S53
Shunekeyeva, А. А.
Fruit-berry fillers in the production of kazakh national fermented milk drinks. [Текст] / А. А. Shunekeyeva, M. K. Alimardanova, A. A. Majorov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №1. - P. 139-146
Рубрики: Пищевые производства
Кл.слова (ненормированные):
ayran -- ermented milk drink -- fruit and berry filler -- goat's milk -- mathematical model -- ozonisation
Аннотация: This paper offers investigation of fruit and berry fillers on the rheological properties of fermented milk drinks. The research was conducted as part of a scientific research effort. Local wild plants were used as fillers. This type of research allowed expanding the range of products at the enterprise and improving the organoleptic and nutritional properties of products. The purpose of this article is to find additional local vegetable raw materials as filler for fermented milk products. The importance of the results is that the data obtained can be used by specialists of dairy farms. During the period of coronavirus infection, when there were interruptions in the supply of raw materials, such directions it sets for future research as the development and improvement new food products by using local plant raw materials were revealed.
Держатели документа:
WKU
Доп.точки доступа:
Alimardanova, M. K.
Majorov, A. A.
526.
Подробнее
42.11
D99
Dzholdasbaeva, G.
Cluster method and interaction mechanisms in the organization of grain production [Текст] / G. Dzholdasbaeva, P. Beisekovа // Доклады национальной академии наук Республики Казахстан. - 2021. - №1. - Р. 119-124
ББК 42.11
Рубрики: Зерновые и зернобобовые культуры
Кл.слова (ненормированные):
кластер -- зерновое производство -- продукция -- механизм -- взаимодействие -- отношения -- услуги -- цены -- субъекты -- участники -- регулирование -- ресурсы
Аннотация: Механизм распределительных отношений по поводу обмена промежуточной продукции, ресурсов и услуг и распределение дохода от реализации конечной продукции на внешнем рынке является важнейшей частью экономических отношений внутри кластера. Распределительный механизм обеспечивает соблюдение интересов субъектов кластера и при этом механизм зернопродуктового кластера основан на том, что доходы от реализации конечной продукции распределены по цепочке технологического цикла, распределяются через цены, тарифы, централизованные фонды, которые созданы участниками кластера. В зернопродуктовом комплексе при использовании рыночных цен часть предприятий становятся прибыльными, одни – убыточными и при кластеризации данные процессы могут сохраняться. Важным звеном регионального зернового кластера являются крупные зерновые компании, холдинги, сосредоточившие крупные хлебоприемные предприятия по приемке, сушке, хранению и отгрузке зерна, они включают высокопроизводительные мукомольные предприятия, располагающие современной техникой международных производителей. В составе данных компаний находятся крупные, средние и мелкие сельскохозяйственные предприятия, производящие зерно, разработавшие свою технологическую стратегию и структуру производства, тактику, поведение на рынке, ценообразовательную политику
Держатели документа:
ЗКУ
Доп.точки доступа:
Beisekovа, P.
D99
Dzholdasbaeva, G.
Cluster method and interaction mechanisms in the organization of grain production [Текст] / G. Dzholdasbaeva, P. Beisekovа // Доклады национальной академии наук Республики Казахстан. - 2021. - №1. - Р. 119-124
Рубрики: Зерновые и зернобобовые культуры
Кл.слова (ненормированные):
кластер -- зерновое производство -- продукция -- механизм -- взаимодействие -- отношения -- услуги -- цены -- субъекты -- участники -- регулирование -- ресурсы
Аннотация: Механизм распределительных отношений по поводу обмена промежуточной продукции, ресурсов и услуг и распределение дохода от реализации конечной продукции на внешнем рынке является важнейшей частью экономических отношений внутри кластера. Распределительный механизм обеспечивает соблюдение интересов субъектов кластера и при этом механизм зернопродуктового кластера основан на том, что доходы от реализации конечной продукции распределены по цепочке технологического цикла, распределяются через цены, тарифы, централизованные фонды, которые созданы участниками кластера. В зернопродуктовом комплексе при использовании рыночных цен часть предприятий становятся прибыльными, одни – убыточными и при кластеризации данные процессы могут сохраняться. Важным звеном регионального зернового кластера являются крупные зерновые компании, холдинги, сосредоточившие крупные хлебоприемные предприятия по приемке, сушке, хранению и отгрузке зерна, они включают высокопроизводительные мукомольные предприятия, располагающие современной техникой международных производителей. В составе данных компаний находятся крупные, средние и мелкие сельскохозяйственные предприятия, производящие зерно, разработавшие свою технологическую стратегию и структуру производства, тактику, поведение на рынке, ценообразовательную политику
Держатели документа:
ЗКУ
Доп.точки доступа:
Beisekovа, P.
527.
Подробнее
46.6
T76
Torekhanov, A. A.
Etti merinos –Kazakhstani export-oriented meat bread [Текст] / A. A. Torekhanov, N. K. Zhumadillayev // Доклады национальной академии наук Республики Казахстан. - 2021. - №1. - Р. 146-151
ББК 46.6
Рубрики: Овцеводство
Кл.слова (ненормированные):
животноводство -- овцеводческая отрасль -- мясная порода -- тонкорунная порода -- продуктивность -- крестьянские хозяйства -- селекция -- генофонд
Аннотация: Овцеводство в Казахстане является традиционной отраслью животноводства. Развитию отрасли способствует наличие больших площадей пастбищных угодий, а также существующий ценный генофонд породных ресурсов, созданный отечественной селекцией и многолетней работой ученых-селекционеров. Республика обладает большим потенциалом для дальнейшего развития овцеводческой отрасли и способна не только удовлетворить потребность населения в баранине, но и стать крупным экспортером. Восстановление и дальнейшее развитие отечественного овцеводства должно основываться на рациональном использовании генетического потенциала животных и природных пастбищ страны для рентабельного производства высококачественной овцеводческой продукции, отвечающей международным стандартам. В статье рассматриваются вопросы развития тонкорунного овцеводства в Алматинской, Жамбылской и Южно-Казахстанской областях, улучшения мясных характеристик Южно-Казахстанского мериноса. Опыт использования баранов-производителей "Етті меринос" в хозяйствах Туркестанской области показал, что мясо баранов- мериносов положительно влияет на мясную продуктивность южноказахских мериносов и в то же время не ухудшает их шерстные характеристики. Представлены сведения по поголовью овец породы «Етті меринос» на 2020 год, классный состав ярок по хозяйствам, продуктивность линейных баранов-производителей, баранов-производителей в ряде поколений, оценка по качеству потомства 6-7 месячных баранчиков, шерстная продуктивность селекционных групп маток.
Держатели документа:
ЗКУ
Доп.точки доступа:
Zhumadillayev, N.K.
T76
Torekhanov, A. A.
Etti merinos –Kazakhstani export-oriented meat bread [Текст] / A. A. Torekhanov, N. K. Zhumadillayev // Доклады национальной академии наук Республики Казахстан. - 2021. - №1. - Р. 146-151
Рубрики: Овцеводство
Кл.слова (ненормированные):
животноводство -- овцеводческая отрасль -- мясная порода -- тонкорунная порода -- продуктивность -- крестьянские хозяйства -- селекция -- генофонд
Аннотация: Овцеводство в Казахстане является традиционной отраслью животноводства. Развитию отрасли способствует наличие больших площадей пастбищных угодий, а также существующий ценный генофонд породных ресурсов, созданный отечественной селекцией и многолетней работой ученых-селекционеров. Республика обладает большим потенциалом для дальнейшего развития овцеводческой отрасли и способна не только удовлетворить потребность населения в баранине, но и стать крупным экспортером. Восстановление и дальнейшее развитие отечественного овцеводства должно основываться на рациональном использовании генетического потенциала животных и природных пастбищ страны для рентабельного производства высококачественной овцеводческой продукции, отвечающей международным стандартам. В статье рассматриваются вопросы развития тонкорунного овцеводства в Алматинской, Жамбылской и Южно-Казахстанской областях, улучшения мясных характеристик Южно-Казахстанского мериноса. Опыт использования баранов-производителей "Етті меринос" в хозяйствах Туркестанской области показал, что мясо баранов- мериносов положительно влияет на мясную продуктивность южноказахских мериносов и в то же время не ухудшает их шерстные характеристики. Представлены сведения по поголовью овец породы «Етті меринос» на 2020 год, классный состав ярок по хозяйствам, продуктивность линейных баранов-производителей, баранов-производителей в ряде поколений, оценка по качеству потомства 6-7 месячных баранчиков, шерстная продуктивность селекционных групп маток.
Держатели документа:
ЗКУ
Доп.точки доступа:
Zhumadillayev, N.K.
528.
Подробнее
35.51
T76
Тorebekov, А. К.
Determination of rem in Uranium ores of the Shu-Sarysu uranium-ore province by inductively coupled plasma atomic emission spectrometry. [Текст] / А. К. Тorebekov, M. S. Kalmakhanova, B. K. Massalimova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 29-35
ББК 35.51
Рубрики: Технология топлива
Кл.слова (ненормированные):
uranium ore -- internal standard -- elemental analysis -- ICP-NPP
Аннотация: This article discusses the features of the determination of elements in uranium ores of the Shusarysu uranium-ore province by inductively coupled plasma atomic emission spectrometry in comparison with the ore standard of Ore Research & Exploration (Australia). A multi-stage method of sample preparation for measurement is considered. The existing and developed methods for determining the elemental composition of uranium ores are focused, as a rule, on the determination of specific elements using regulated analysis procedures. However, during routine analysis, we need to quickly and efficiently determine a larger list of elements available with one instrumental method. Various methods are used to obtain multielement analysis, among which mass spectrometry and inductively coupled plasma atomic emission analysis are most popular due to their high performance and low detection limits. The listed methods work with solutions, therefore, it is necessary to pay great attention to sample preparation and instrument calibration.
Держатели документа:
WKU
Доп.точки доступа:
Kalmakhanova, M. S.
Massalimova, B. K.
T76
Тorebekov, А. К.
Determination of rem in Uranium ores of the Shu-Sarysu uranium-ore province by inductively coupled plasma atomic emission spectrometry. [Текст] / А. К. Тorebekov, M. S. Kalmakhanova, B. K. Massalimova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 29-35
Рубрики: Технология топлива
Кл.слова (ненормированные):
uranium ore -- internal standard -- elemental analysis -- ICP-NPP
Аннотация: This article discusses the features of the determination of elements in uranium ores of the Shusarysu uranium-ore province by inductively coupled plasma atomic emission spectrometry in comparison with the ore standard of Ore Research & Exploration (Australia). A multi-stage method of sample preparation for measurement is considered. The existing and developed methods for determining the elemental composition of uranium ores are focused, as a rule, on the determination of specific elements using regulated analysis procedures. However, during routine analysis, we need to quickly and efficiently determine a larger list of elements available with one instrumental method. Various methods are used to obtain multielement analysis, among which mass spectrometry and inductively coupled plasma atomic emission analysis are most popular due to their high performance and low detection limits. The listed methods work with solutions, therefore, it is necessary to pay great attention to sample preparation and instrument calibration.
Держатели документа:
WKU
Доп.точки доступа:
Kalmakhanova, M. S.
Massalimova, B. K.
529.
Подробнее
35
D99
Dzhumadullaeva, S. A.
The kinetics of selective hydrazinolysis of maleic acid on the acid catalyst. [Текст] / S. A. Dzhumadullaeva, A. B. Bayeshov, A. V. Kolesnikov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 53-57
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
maleic acid -- hydrazinolysis -- hydrazide -- catalyst
Аннотация: For the first time, kinetics and the mechanism of the reaction of hydrazinolysis of maleic acid in the presence of cation exchanger resin KU-2-8 in H-form have been studied. The experiments were carried out in a static system in a thermostat glass reactor. It was found that cation exchanger shows high catalytic activity in the studied process - maleic acid conversion was 93%, and maleic hydrazide yield was 90%. The conversion selectivity of maleic acid to maleic hydrazide was 97,8%. The reaction rate was determined from the accumulation of maleic hydrazide. The apparent reaction rate constant (k) was calculated from the second-order reaction rate equation. The effect of initial concentrations of maleic acid and hydrazine hydrate, the temperature on the reaction rate was studied. The first order of maleic acid and hydrazine hydrate is determined. Activation energy of the process found from the Arrhenius dependence is 32,1 kJ/mol. On the basis of kinetic and IR spectroscopic methods, a probable reaction mechanism involving polymer-bound hydrogen ions is proposed.
Держатели документа:
WKU
Доп.точки доступа:
Bayeshov, A.B.
Kolesnikov, A.V.
D99
Dzhumadullaeva, S. A.
The kinetics of selective hydrazinolysis of maleic acid on the acid catalyst. [Текст] / S. A. Dzhumadullaeva, A. B. Bayeshov, A. V. Kolesnikov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 53-57
Рубрики: chemical Technology
Кл.слова (ненормированные):
maleic acid -- hydrazinolysis -- hydrazide -- catalyst
Аннотация: For the first time, kinetics and the mechanism of the reaction of hydrazinolysis of maleic acid in the presence of cation exchanger resin KU-2-8 in H-form have been studied. The experiments were carried out in a static system in a thermostat glass reactor. It was found that cation exchanger shows high catalytic activity in the studied process - maleic acid conversion was 93%, and maleic hydrazide yield was 90%. The conversion selectivity of maleic acid to maleic hydrazide was 97,8%. The reaction rate was determined from the accumulation of maleic hydrazide. The apparent reaction rate constant (k) was calculated from the second-order reaction rate equation. The effect of initial concentrations of maleic acid and hydrazine hydrate, the temperature on the reaction rate was studied. The first order of maleic acid and hydrazine hydrate is determined. Activation energy of the process found from the Arrhenius dependence is 32,1 kJ/mol. On the basis of kinetic and IR spectroscopic methods, a probable reaction mechanism involving polymer-bound hydrogen ions is proposed.
Держатели документа:
WKU
Доп.точки доступа:
Bayeshov, A.B.
Kolesnikov, A.V.
530.
Подробнее
26.3
S14
Safarov, R. Z.
Elemental analysis of local and foreign raw materials for the production of trimanganese tetraoxide pigment. [Текст] / R. Z. Safarov, A. Zhandildenova, D. B. Kargin, B. B. Makhmutov [и др.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 92-98
ББК 26.3
Рубрики: geology
Кл.слова (ненормированные):
hausmannite -- pigment -- manganese ore -- nanopowders -- electronic microscopy -- energy-dispersive analysis
Аннотация: In the course of continuation of scientific research in the development of Kazakhstani technology for the production of trimanganese tetraoxide pigment, there have been proposed new methods of analysis which make it possible to investigate new nanostructural materials sourced from local deposits. The results obtained are of practical importance and serve as the foundation for developing new technologically advanced domestic production of a competitive product that is in demand both on the national and international markets. The available methods are not able to highlight the particularity and diversity of Kazakhstani manganese ores due to the uneven distribution of manganese minerals and host (waste) rock, the quantitative ratio of rock-forming components and their variation instability. Methods of energy-dispersive analysis of manganese ores from Kazakhstani Zhaksylyk and Bogach deposits have been put forward, electronic micrographs, spectrograms of samples, diagrams of normalized distribution of elements on the surface of samples have been obtained and a comparative analysis with raw analogue samples of some foreign manufacturers has been performed.
Держатели документа:
WKU
Доп.точки доступа:
Zhandildenova, A.
Kargin, D. B.
Makhmutov, B. B.
Kamatov, R. M.
Shomanova, Zh. K.
S14
Safarov, R. Z.
Elemental analysis of local and foreign raw materials for the production of trimanganese tetraoxide pigment. [Текст] / R. Z. Safarov, A. Zhandildenova, D. B. Kargin, B. B. Makhmutov [и др.] // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 92-98
Рубрики: geology
Кл.слова (ненормированные):
hausmannite -- pigment -- manganese ore -- nanopowders -- electronic microscopy -- energy-dispersive analysis
Аннотация: In the course of continuation of scientific research in the development of Kazakhstani technology for the production of trimanganese tetraoxide pigment, there have been proposed new methods of analysis which make it possible to investigate new nanostructural materials sourced from local deposits. The results obtained are of practical importance and serve as the foundation for developing new technologically advanced domestic production of a competitive product that is in demand both on the national and international markets. The available methods are not able to highlight the particularity and diversity of Kazakhstani manganese ores due to the uneven distribution of manganese minerals and host (waste) rock, the quantitative ratio of rock-forming components and their variation instability. Methods of energy-dispersive analysis of manganese ores from Kazakhstani Zhaksylyk and Bogach deposits have been put forward, electronic micrographs, spectrograms of samples, diagrams of normalized distribution of elements on the surface of samples have been obtained and a comparative analysis with raw analogue samples of some foreign manufacturers has been performed.
Держатели документа:
WKU
Доп.точки доступа:
Zhandildenova, A.
Kargin, D. B.
Makhmutov, B. B.
Kamatov, R. M.
Shomanova, Zh. K.
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