База данных: Статьи
Страница 72, Результатов: 839
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711.
Подробнее
24
I-53
Ikhsanov, Y. S.
Amino acid and vitamin composition of crataegus orientalis pall. [Текст] / Y. S. Ikhsanov, K. M. Kusainova, G. Y. Tasmagambetova, N. T. Andasova, Y. A. Litvinenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 149-154
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
Crataegus -- Crataegus orientalis Pall -- amino acids -- vitamins -- SFE extraction
Аннотация: This article examines the study of the quantitative composition of amino acids and vitamins in the fruits of the species of the genus Crataegus widespread in Kazakhstan in a supercritical extract isolated and the fruits of the Crataegus orientalis Pall plant, in order to establish the possibility of using and with subsequent cultivation of the selected species.
Держатели документа:
WKU
Доп.точки доступа:
Kusainova, K. M.
Tasmagambetova, G. Y.
Andasova, N. T.
Litvinenko, Y. A.
I-53
Ikhsanov, Y. S.
Amino acid and vitamin composition of crataegus orientalis pall. [Текст] / Y. S. Ikhsanov, K. M. Kusainova, G. Y. Tasmagambetova, N. T. Andasova, Y. A. Litvinenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 149-154
Рубрики: chemistry
Кл.слова (ненормированные):
Crataegus -- Crataegus orientalis Pall -- amino acids -- vitamins -- SFE extraction
Аннотация: This article examines the study of the quantitative composition of amino acids and vitamins in the fruits of the species of the genus Crataegus widespread in Kazakhstan in a supercritical extract isolated and the fruits of the Crataegus orientalis Pall plant, in order to establish the possibility of using and with subsequent cultivation of the selected species.
Держатели документа:
WKU
Доп.точки доступа:
Kusainova, K. M.
Tasmagambetova, G. Y.
Andasova, N. T.
Litvinenko, Y. A.
712.
Подробнее
28.5
S68
Smailova, K. S.
Obtaining flavonoid from taraxacum Kok-saghyz rodin plant growing in Kazakhstan. [Текст] / K. S. Smailova, G.E. Azimbaeva, A. A. Bakibaev, M. S. Abdikerim // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 155-160
ББК 28.5
Рубрики: Botany
Кл.слова (ненормированные):
medicinal plants -- Taraxacum koksaghyz rodin -- biologically active substances -- flavonoids -- IR spectrum -- 13С -NMR
Аннотация: In recent years, the interest of researchers in the herbal preparation has grown significantly. Plants are sources of biologically active substances (BAS). In previous articles, the chemical composition and biologically active substances of plants endemic Taraxacum kok-saghyz Rodin growing in Kazakhstan has been studied. Among the BAS of plant origin, inulin and flavonoids occupy a special place. The article examines the release of inulin and flavonoid from the stem of Taraxacum kok-saghyz Rodin plants. In order to isolate a flavonoid, you first need to extract inulin. Due to the fact that in our plants, inulin accumulates up to 40%. Therefore, the first stage was to isolate inulin: with extractions 1:10 with distilled water for 60 minutes, and in the second stage, the further isolation of the residue was first dried, the dry residue was 1:10 with a ratio of 70% ethanol for 3 hours. The inulin yield was -5%, the melting point was 1300C. A The yield of flavanoid is 0.66%, the melting point is 1700 C, the aggregate state is acicular light brown light. The structure of the isolated flavonoid was determined on a Uviline 9100 spectro-photometer; the highest absorption was observed at a wavelength of 364 nm. Consequently, the structure of the isolated flavonoid coincides with the literature data. The maxima of the UV, IR, 13С -NMR. spectrum show that flavonol is a derivative.
Держатели документа:
WKU
Доп.точки доступа:
Azimbaeva, G.E.
Bakibaev, A.A.
Abdikerim, M.S.
S68
Smailova, K. S.
Obtaining flavonoid from taraxacum Kok-saghyz rodin plant growing in Kazakhstan. [Текст] / K. S. Smailova, G.E. Azimbaeva, A. A. Bakibaev, M. S. Abdikerim // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №2. - P. 155-160
Рубрики: Botany
Кл.слова (ненормированные):
medicinal plants -- Taraxacum koksaghyz rodin -- biologically active substances -- flavonoids -- IR spectrum -- 13С -NMR
Аннотация: In recent years, the interest of researchers in the herbal preparation has grown significantly. Plants are sources of biologically active substances (BAS). In previous articles, the chemical composition and biologically active substances of plants endemic Taraxacum kok-saghyz Rodin growing in Kazakhstan has been studied. Among the BAS of plant origin, inulin and flavonoids occupy a special place. The article examines the release of inulin and flavonoid from the stem of Taraxacum kok-saghyz Rodin plants. In order to isolate a flavonoid, you first need to extract inulin. Due to the fact that in our plants, inulin accumulates up to 40%. Therefore, the first stage was to isolate inulin: with extractions 1:10 with distilled water for 60 minutes, and in the second stage, the further isolation of the residue was first dried, the dry residue was 1:10 with a ratio of 70% ethanol for 3 hours. The inulin yield was -5%, the melting point was 1300C. A The yield of flavanoid is 0.66%, the melting point is 1700 C, the aggregate state is acicular light brown light. The structure of the isolated flavonoid was determined on a Uviline 9100 spectro-photometer; the highest absorption was observed at a wavelength of 364 nm. Consequently, the structure of the isolated flavonoid coincides with the literature data. The maxima of the UV, IR, 13С -NMR. spectrum show that flavonol is a derivative.
Держатели документа:
WKU
Доп.точки доступа:
Azimbaeva, G.E.
Bakibaev, A.A.
Abdikerim, M.S.
713.
Подробнее
36
A53
Anarbekova, Z. А.
The influence of yeast races on the aroma-forming substances of table wines. [Текст] / Z. А. Anarbekova, G. I. Baigazieva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 12-18
ББК 36
Рубрики: Пищевое производство
Кл.слова (ненормированные):
Wine yeast -- fermentation -- enzyme activity -- ermentation dynamics -- organic acids -- aroma-forming substances.
Аннотация: This article shows the influence of the yeast race on the fermentation dynamics of white grape must, the composition of organic acids and aroma-forming components. The races that ensure the production of high-quality wine materials are identified.
Держатели документа:
WKU
Доп.точки доступа:
Baigazieva, G.I.
A53
Anarbekova, Z. А.
The influence of yeast races on the aroma-forming substances of table wines. [Текст] / Z. А. Anarbekova, G. I. Baigazieva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 12-18
Рубрики: Пищевое производство
Кл.слова (ненормированные):
Wine yeast -- fermentation -- enzyme activity -- ermentation dynamics -- organic acids -- aroma-forming substances.
Аннотация: This article shows the influence of the yeast race on the fermentation dynamics of white grape must, the composition of organic acids and aroma-forming components. The races that ensure the production of high-quality wine materials are identified.
Держатели документа:
WKU
Доп.точки доступа:
Baigazieva, G.I.
714.
Подробнее
35
A92
Augaliev, D. B.
Oxidative dimerization of methane to C2 hydrocarbons. [Текст] / D. B. Augaliev, M. K. Erkibaeva, A. O. Aidarova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 18-24
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
ODM reaction -- C2 hydrocarbons -- SHS method -- temperature of reaction
Аннотация: The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce-20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction.
Держатели документа:
WKU
Доп.точки доступа:
Erkibaeva, M.K.
Aidarova, A.O.
Tungatarova, S.А.
Baizhumanova, T.S.
A92
Augaliev, D. B.
Oxidative dimerization of methane to C2 hydrocarbons. [Текст] / D. B. Augaliev, M. K. Erkibaeva, A. O. Aidarova // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 18-24
Рубрики: chemical Technology
Кл.слова (ненормированные):
ODM reaction -- C2 hydrocarbons -- SHS method -- temperature of reaction
Аннотация: The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce-20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction.
Держатели документа:
WKU
Доп.точки доступа:
Erkibaeva, M.K.
Aidarova, A.O.
Tungatarova, S.А.
Baizhumanova, T.S.
715.
Подробнее
28.5
I-53
Ikhsanov, Y. S.
Amino acid , fatty acid and vitamin composition of rosa caninal. [Текст] / Y. S. Ikhsanov, K.M. Kusainova, G. Y. Tasmagambetova, N. T. Andasova, Y. A. Litvinenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 39-43
ББК 28.5
Рубрики: Botany
Кл.слова (ненормированные):
Rosa -- Rosa canina L -- Supercritical fluid extraction -- amino acid -- vitamins
Аннотация: This article examines the study of the quantitative composition of amino acids and vitamins in the fruits of the species of the genus Rosa widespread in Kazakhstan in the supercritical extract, isolated and the fruits of the Rosa canina plant, in order to establish the possibility of using and with the subsequent cultivation of the selected species.
Держатели документа:
WKU
Доп.точки доступа:
Kusainova, K.M.
Tasmagambetova, G.Y.
Andasova, N.T.
Litvinenko, Y.A.
I-53
Ikhsanov, Y. S.
Amino acid , fatty acid and vitamin composition of rosa caninal. [Текст] / Y. S. Ikhsanov, K.M. Kusainova, G. Y. Tasmagambetova, N. T. Andasova, Y. A. Litvinenko // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 39-43
Рубрики: Botany
Кл.слова (ненормированные):
Rosa -- Rosa canina L -- Supercritical fluid extraction -- amino acid -- vitamins
Аннотация: This article examines the study of the quantitative composition of amino acids and vitamins in the fruits of the species of the genus Rosa widespread in Kazakhstan in the supercritical extract, isolated and the fruits of the Rosa canina plant, in order to establish the possibility of using and with the subsequent cultivation of the selected species.
Держатели документа:
WKU
Доп.точки доступа:
Kusainova, K.M.
Tasmagambetova, G.Y.
Andasova, N.T.
Litvinenko, Y.A.
716.
Подробнее
35
J21
Jalmakhanbetova, R.I.
Calculate the standard enthalpies of combustion , formation and melting of the complex roseofungin with a-, B- and y- cyclodextrin. [Текст] / R.I. Jalmakhanbetova, Ye. M. Suleimen, B. K. Kasenov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 44-47
ББК 35
Рубрики: chemical Technology
Кл.слова (ненормированные):
roseofungin -- cyclodextrin -- standard enthalpy of combustion -- standard enthalpy of formation -- enthalpy of melting of a complex
Аннотация: One of the most important quantities in chemical thermodynamics and thermochemistry is the enthalpy of combustion. Of the currently existing methods for calculating the heat of combustion of natural and synthetic organic compounds, the most acceptable and correct in our case was the Karash method. In this study, the standard enthalpy of combustion, the standard enthalpy of formation, and the melting enthalpy of the antibiotic roseofungin and its cyclodextrin derivatives were calculated. As a result of the study, the thermodynamic constants of the standard enthalpies of combustion, standard enthalpies of formation, and the enthalpies of melting of the above compounds were calculated, which are of interest for physicochemical modeling of processes with their participation, serve as initial information arrays for loading into fundamental thermodynamic data banks and reference books, and is also important for standardization and certification of these complexes. It should be noted that the presence of a large number of hydroxyl groups in the structures of the studied complexes allows them to be attributed to polar compounds.
Держатели документа:
WKU
Доп.точки доступа:
Suleimen, Ye.M.
Kasenov, B.K.
J21
Jalmakhanbetova, R.I.
Calculate the standard enthalpies of combustion , formation and melting of the complex roseofungin with a-, B- and y- cyclodextrin. [Текст] / R.I. Jalmakhanbetova, Ye. M. Suleimen, B. K. Kasenov // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 44-47
Рубрики: chemical Technology
Кл.слова (ненормированные):
roseofungin -- cyclodextrin -- standard enthalpy of combustion -- standard enthalpy of formation -- enthalpy of melting of a complex
Аннотация: One of the most important quantities in chemical thermodynamics and thermochemistry is the enthalpy of combustion. Of the currently existing methods for calculating the heat of combustion of natural and synthetic organic compounds, the most acceptable and correct in our case was the Karash method. In this study, the standard enthalpy of combustion, the standard enthalpy of formation, and the melting enthalpy of the antibiotic roseofungin and its cyclodextrin derivatives were calculated. As a result of the study, the thermodynamic constants of the standard enthalpies of combustion, standard enthalpies of formation, and the enthalpies of melting of the above compounds were calculated, which are of interest for physicochemical modeling of processes with their participation, serve as initial information arrays for loading into fundamental thermodynamic data banks and reference books, and is also important for standardization and certification of these complexes. It should be noted that the presence of a large number of hydroxyl groups in the structures of the studied complexes allows them to be attributed to polar compounds.
Держатели документа:
WKU
Доп.точки доступа:
Suleimen, Ye.M.
Kasenov, B.K.
717.
Подробнее
24
K17
Кairbekov, Zh. К.
Physicochemical and antioxidant properties of humic acids of low-mineralized peloids of the Tuzkol deposit. [Текст] / Zh. К. Кairbekov, I. M. Jeldybayeva, D. Z. Аbilmazhinova, S. M. Suimbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 48-53
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
Low-mineralized sludge sulphide mud (peloids) -- humic -- fulvic -- hymatomelanic -- humic acids -- antioxidant activity
Аннотация: As a result of studies it was found that the peloids of the deposit of Tuzkol Lake (Republic of Kazakhstan) are high quality medium-sulfide, weakly alkaline sludge muds. It was found that peloid-derived humic acid contains 49.63 % oxygen, 22.37% carbon, 9.65 % silicon and 6.26% calcium; it also contains Na, Mg, Al, Fe and an insignificant amount of S, Cl, K, F. Electron microscopy and IR spectroscopy analysis of the molecular structure of humic substances of peloids indicated that their macromolecule consists of framework olefinic and aromatic fragments with a substantial proportion of unoxidized aliphatic groups, as well as aromatic structures containing carboxyl groups. The findings of amperometric detection of the antioxidant properties of humic acids suggest that they have antioxidant activity, which will make it possible to use them as a biologically active substance for medicines.
Держатели документа:
WKU
Доп.точки доступа:
Jeldybayeva, I.M.
Аbilmazhinova, D.Z.
Suimbayeva, S.M.
K17
Кairbekov, Zh. К.
Physicochemical and antioxidant properties of humic acids of low-mineralized peloids of the Tuzkol deposit. [Текст] / Zh. К. Кairbekov, I. M. Jeldybayeva, D. Z. Аbilmazhinova, S. M. Suimbayeva // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 48-53
Рубрики: chemistry
Кл.слова (ненормированные):
Low-mineralized sludge sulphide mud (peloids) -- humic -- fulvic -- hymatomelanic -- humic acids -- antioxidant activity
Аннотация: As a result of studies it was found that the peloids of the deposit of Tuzkol Lake (Republic of Kazakhstan) are high quality medium-sulfide, weakly alkaline sludge muds. It was found that peloid-derived humic acid contains 49.63 % oxygen, 22.37% carbon, 9.65 % silicon and 6.26% calcium; it also contains Na, Mg, Al, Fe and an insignificant amount of S, Cl, K, F. Electron microscopy and IR spectroscopy analysis of the molecular structure of humic substances of peloids indicated that their macromolecule consists of framework olefinic and aromatic fragments with a substantial proportion of unoxidized aliphatic groups, as well as aromatic structures containing carboxyl groups. The findings of amperometric detection of the antioxidant properties of humic acids suggest that they have antioxidant activity, which will make it possible to use them as a biologically active substance for medicines.
Держатели документа:
WKU
Доп.точки доступа:
Jeldybayeva, I.M.
Аbilmazhinova, D.Z.
Suimbayeva, S.M.
718.
Подробнее
24
M23
Mamyrbekova, А.
Study of kinetics of copper oxidation by electrolysis under non-stationary conditions. [Текст] / А. Mamyrbekova, А. Mamyrbekova, M. К. Kassymova, A. Zh. Aitbayeva, O. N. Chechina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 54-59
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
copper electro-oxidation -- copper (I) oxide -- copper (II) oxide -- unsteady electrolysis -- electrolyte -- polarisation curves
Аннотация: The nature of the anion electrolyte affects the rate of copper anodic oxidation, while the process occurs more efficiently in solutions of sulfate and sodium chloride and is accompanied by significant polarisation. Based on the study of kinetics the possibility of obtaining powders of metal oxide was shown, which further allowed to determine the parameters of the electrolysis process in non-stationary conditions in order to obtain highly dispersed materials based on copper oxides with specific physico-chemical properties.
Держатели документа:
WKU
Доп.точки доступа:
Mamyrbekova, А.
Kassymova, M.К.
Aitbayeva, A.Zh.
Chechina, O.N.
M23
Mamyrbekova, А.
Study of kinetics of copper oxidation by electrolysis under non-stationary conditions. [Текст] / А. Mamyrbekova, А. Mamyrbekova, M. К. Kassymova, A. Zh. Aitbayeva, O. N. Chechina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 54-59
Рубрики: chemistry
Кл.слова (ненормированные):
copper electro-oxidation -- copper (I) oxide -- copper (II) oxide -- unsteady electrolysis -- electrolyte -- polarisation curves
Аннотация: The nature of the anion electrolyte affects the rate of copper anodic oxidation, while the process occurs more efficiently in solutions of sulfate and sodium chloride and is accompanied by significant polarisation. Based on the study of kinetics the possibility of obtaining powders of metal oxide was shown, which further allowed to determine the parameters of the electrolysis process in non-stationary conditions in order to obtain highly dispersed materials based on copper oxides with specific physico-chemical properties.
Держатели документа:
WKU
Доп.точки доступа:
Mamyrbekova, А.
Kassymova, M.К.
Aitbayeva, A.Zh.
Chechina, O.N.
719.
Подробнее
36
M15
Madet, G.
Research of malting properties of Kasakhstan tritikale grain varieties for use in the beverage industry. [Текст] / G. Madet // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 59-65
ББК 36
Рубрики: Пищевые производства
Кл.слова (ненормированные):
Malt -- barley -- triticale -- fermentation industry -- kvass -- kvass wort concentrate -- ethyl alcohol -- extract -- variety -- germination ability
Аннотация: In this regard, it is obvious that the performance of work related to theoretical and experimental research aimed at the development of new technological modes of preparation of malt from triticale is one of the urgent tasks, the decision of which, to create an assortment of drinks. The purpose of the research work is to study the malting properties of Kazakhstani varieties of triticale grain.
Держатели документа:
WKU
Доп.точки доступа:
Bayazitova, M.M.
M15
Madet, G.
Research of malting properties of Kasakhstan tritikale grain varieties for use in the beverage industry. [Текст] / G. Madet // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 59-65
Рубрики: Пищевые производства
Кл.слова (ненормированные):
Malt -- barley -- triticale -- fermentation industry -- kvass -- kvass wort concentrate -- ethyl alcohol -- extract -- variety -- germination ability
Аннотация: In this regard, it is obvious that the performance of work related to theoretical and experimental research aimed at the development of new technological modes of preparation of malt from triticale is one of the urgent tasks, the decision of which, to create an assortment of drinks. The purpose of the research work is to study the malting properties of Kazakhstani varieties of triticale grain.
Держатели документа:
WKU
Доп.точки доступа:
Bayazitova, M.M.
720.
Подробнее
24
M97
Mussina, А. S.
Development of the conditions for strong thallium amalgam. [Текст] / А. S. Mussina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 65-70
ББК 24
Рубрики: chemistry
Кл.слова (ненормированные):
thallium amalgam -- chemical preparation -- storage -- decomposition -- sulfuric acid -- water -- wash liquid
Аннотация: It has been established that lNH2SO4 solution and distilled water can be used as a protective medium for a long-term storage (30-40 days) of thallium amalgam of eutectic composition (8.6 mas.%), without sliming of its surface and an insignificant change of its concentration. An inverse dependence between the decomposition reaction rate and the ratio of the solution volume per unit of the contact surface (V:S), which corresponds to the height of the liquid layer (h) above the amalgam, is observed. At h ~ 2.5 cm and higher, the reaction rate becomes stabilized. The value of metal loss during its storage for 10-15 days does not exceed 0.5-1.0 mas.% of the initial thallium content in the amalgam. It has been shown that the rate of dissolution of thallium from amalgam is rather low, and in sulfuric acid solution it is only slightly higher than that in water with all S:V ratios. A similar picture is observed upon thallium amalgam decomposition in the same media in an open vessel; the difference consists only in a higher K value (Table 4). Thus, with S:V = 1:2.5, in an open vessel K in lNH2SO4 makes up 10,5.1011 mol/cm2.sec, and in H2O – 7.3.1011 mol/cm2.sec, whereas in a closed vessel K in lNH2SO4 makes up 1,9.1011 mol/cm2.sec, and in H2O – 1.5.1011 mol/cm2.sec. For 40 days of thallium amalgam (8.54 mas.%) storage in 1NH2SO4 the loss of thallium has been 1.3 mas.%, and in the distilled water - 1 mas.%. The quantity of the dissolved metal increases in proportion to the experiment duration, which is characteristic for a zero-order reaction, and this dependence is observed for all S:V ratios from 1:1 to 1:7. Besides, a possibility to use some saturated hydrocarbons, wherein no sliming of thallium amalgam occurs, as a protective wash liquid has been shown.
Держатели документа:
WKU
Доп.точки доступа:
Baitasheva, G.U.
Myrzakhmetova, N.О.
Tagabergenova, Zh.A.
Gorbulicheva , E.P.
M97
Mussina, А. S.
Development of the conditions for strong thallium amalgam. [Текст] / А. S. Mussina // News of national academy of sciences of the republic of Kazakhstan. . - 2021. - №3. - P. 65-70
Рубрики: chemistry
Кл.слова (ненормированные):
thallium amalgam -- chemical preparation -- storage -- decomposition -- sulfuric acid -- water -- wash liquid
Аннотация: It has been established that lNH2SO4 solution and distilled water can be used as a protective medium for a long-term storage (30-40 days) of thallium amalgam of eutectic composition (8.6 mas.%), without sliming of its surface and an insignificant change of its concentration. An inverse dependence between the decomposition reaction rate and the ratio of the solution volume per unit of the contact surface (V:S), which corresponds to the height of the liquid layer (h) above the amalgam, is observed. At h ~ 2.5 cm and higher, the reaction rate becomes stabilized. The value of metal loss during its storage for 10-15 days does not exceed 0.5-1.0 mas.% of the initial thallium content in the amalgam. It has been shown that the rate of dissolution of thallium from amalgam is rather low, and in sulfuric acid solution it is only slightly higher than that in water with all S:V ratios. A similar picture is observed upon thallium amalgam decomposition in the same media in an open vessel; the difference consists only in a higher K value (Table 4). Thus, with S:V = 1:2.5, in an open vessel K in lNH2SO4 makes up 10,5.1011 mol/cm2.sec, and in H2O – 7.3.1011 mol/cm2.sec, whereas in a closed vessel K in lNH2SO4 makes up 1,9.1011 mol/cm2.sec, and in H2O – 1.5.1011 mol/cm2.sec. For 40 days of thallium amalgam (8.54 mas.%) storage in 1NH2SO4 the loss of thallium has been 1.3 mas.%, and in the distilled water - 1 mas.%. The quantity of the dissolved metal increases in proportion to the experiment duration, which is characteristic for a zero-order reaction, and this dependence is observed for all S:V ratios from 1:1 to 1:7. Besides, a possibility to use some saturated hydrocarbons, wherein no sliming of thallium amalgam occurs, as a protective wash liquid has been shown.
Держатели документа:
WKU
Доп.точки доступа:
Baitasheva, G.U.
Myrzakhmetova, N.О.
Tagabergenova, Zh.A.
Gorbulicheva , E.P.
Страница 72, Результатов: 839